The salt solution is prepared in wooden tanks from coarse clean salt
(ground rock salt is unsuitable), containing as little iron as possible,
in the proportion of 50 pounds to 100 gallons of water. After passing
through a gravel or other suitable filter the brine solution is carried
by brass pipes to the electrolyser. The rate of flow is adjusted to the
temperature of the hypochlorite solution leaving the cell but under
normal conditions it is stated that the cell described will pass 40
gallons per hour with a consumption of 70 amperes and produce 2-1/2
pounds of chlorine per hour. This is equal to 8 pounds of salt and 3.08
kilowatt hours per pound of chlorine. After the cells have been operated
for several months the efficiency usually falls and 10-11 pounds of salt
and 3.5-3.7 kilowatt hours are required for the production of one pound
of chlorine. The concentration of the hypochlorite solution is usually
about 6 grams per litre.
Rickard[3] stated that by cooling the Dayton cell with ice 1 pound of
chlorine could be produced from 2.65 kilowatt hours and 6.9 pounds of
sodium chloride; without cooling the figures were 3.62 kilowatt hours
and 7.2 pounds of salt. Based on the figures that have been obtained
from mature cells, the efficiency of the Dayton cell as compared with
those described by Kershaw is as follows:
------------------+----------------------+----------------------
| SALT. | POWER.
| PER POUND OF AVAILABLE CHLORINE.
Type of Cell. +----------+-----------+----------+-----------
| Pounds. | Per Cent | Kilowatt | Efficiency
| | Consumed. | Hours. | Per Cent.
------------------+----------+-----------+----------+-----------
Haas and Oettel | 10.7 | 15.4 | 3.8 | 31.9
Kellner | 7.5 | 22.0 | 2.75 | 43.9
Hermite | 11.2 | 14.5 | 2.87 | 42.2
Mather and Platt | .... | .... | 2.75 | 43.9
Dayton | 10.0 | 16.5 | 3.6 | 33.6
Theoretical | 1.65 | 100.0 | 1.21 | 100.0
------------------+----------+-----------+----------+-----------
The cost of production depends upon local conditions: if alternating
current is available at $30 per horse-power per annum, and low-grade
salt can be obtained for $5 per ton the cost of 1 pound of chlorine
would be
-----------------+----------------------------
| COST (CENTS) PER POUND OF
| AVAILABLE CHLORINE.
Type of Cell. +--------+----------+--------
| Salt. | Current. | Total.
-----------------+--------+----------+--------
Haas and Oettel | 2.67 | 1.97 | 4.64
Kellner | 1.87 | 1.43 | 3.30
Hermite | 2.80 | 1.49 | 4.29
Dayton | 2.50 | 1.92 | 4.42
-----------------+--------+----------+--------
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