The electrical and chemical efficiencies of the Haas and Oettel and
Dayton cells, which contain carbon electrodes, are smaller than those
containing platinum electrodes but for water sterilisation the carbon
cells have been found to be more suitable. To prevent the action of
magnesium salts on the platinum electrodes it is necessary to use a
higher grade of salt or to provide means of purification. Because of the
absence of a base and the presence of chlorides, electrolytic
hypochlorite cannot be stored for more than a few hours without
appreciable loss of titre. Unless used for the treatment of the effluent
of a filter plant operated at a fairly constant rate a small storage
tank is necessary to compensate for the irregular demand and to provide
the head required by orifice feed boxes. Small variations can be made by
regulating the flow through the cells but large ones are not compatible
with efficiency, which is the highest under a constant load.
Claims have been made that electrolytic hypochlorite is more efficient
as a germicide than bleach when compared on the basis of their available
chlorine content but no evidence of it has been produced. Bleach
contains an excess of base, which retards the germicidal action, and
electrolytic hypochlorite contains an excess of sodium chloride, which
accelerates it (Race[4]) but the ultimate effect is the same with both.
This is shown in Table XXIV.
TABLE XXIV.[A]--COMPARISON OF BLEACH WITH ELECTROLYTIC HYPOCHLORITE
----------------+-------------------++-------------------
| BLEACH. || ELECTROLYTIC
| || HYPOCHLORITE.
+-------------------++-------------------
Contact Period. | Available Chlorine. Parts Per Million.
+---------+---------++---------+---------
| 0.4 | 0.6 || 0.4 | 0.6
----------------+---------+---------++---------+---------
Nil | 182 | ... || ... | ...
10 minutes | 130 | 10 || 120 | 8
1 hour | 66 | 1 || 60 | 0
2 hours | 3 | 0 || 1 | 0
3-1/2 hours | 0 | 0 || 0 | 0
----------------+---------+---------++---------+---------
[A] Results are B. coli per 10 c.cms.
Electrolytic hypochlorite has a greater germicidal velocity than bleach
but the difference is so small as to be of no practical importance.
Rabs[5] experimented with various hypochlorites but was unable to find
any appreciable differences in their germicidal action.
Public-domain text, read in full here on John Shaqi.
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