At the time when the abnormal results were obtained with ammonium
hypochlorite and mixtures of bleach and ammonia, the phenomenon appeared
to be of scientific interest only and especially so as Rideal had
attributed the obnoxious tastes and odours, sometimes produced by
chlorination, to the formation of chloramines. During the winter of
1915-1916 the price of bleach, however, advanced to extraordinary
heights and the author then determined to try out the process on a
practical scale for the purification of water. A subsidiary plant
pumping about 200,000 Imperial gallons per day (240,000 U. S. A.
gallons) was found to be available for this purpose and the chloramine
process was substituted for the bleach method previously in operation.
The process was commenced by the addition of pure ammonia fort, in the
amount required to give a chlorine to ammonia ratio of 2:1, to the
bleach solutions in the barrels. The results were not in accordance with
those obtained in the laboratory and it was found that the samples of
bleach solutions received for analysis were far below the strength
calculated from the amount of dry bleach used. This experience was
repeated on subsequent days and the deficiency was found to increase on
increasing the ammonia dosage. Solutions of similar concentration were
then used in the laboratory with similar losses, and it was observed
that on the addition of ammonia a copious evolution of gas occurred. An
investigation showed that the ammonia and bleach must be mixed as dilute
solutions and prolonged contact avoided (_vide_ p. 127). Alterations
were accordingly made in the plant and the bleach and ammonia were
prepared as dilute solutions in separate vessels and allowed to mix for
only a few seconds before delivery to the suction of the pumps. This
method of application was instantaneously successful and results equal
to those obtained in the laboratory were at once secured. The dosage was
reduced until the bacteriological results were adversely affected and
continued at values slightly in excess of this figure (0.15 p.p.m.) for
a short period to prove that the process was reliable.
From a consideration of the work of Raschig and Rideal, it appeared that
the most efficient proportions of available chlorine and ammonia would
be two parts by weight of the former to one part of the latter and this
ratio was maintained during the run on the experimental plant. Lower
ratios of chlorine to ammonia were contra-indicated by the laboratory
experiments, which showed that the efficiency was not increased thereby
whilst higher ratios were left for future consideration.
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