During the period of nine months covered by the results in Table XXIX,
only five cases of typhoid fever were reported in which the evidence did
not clearly indicate that the infection had occurred outside the city.
The reduction in the bleach consumed during the same period effected a
saving of $3,200.
During one period of operation the hypochlorite dosage was gradually
reduced to ascertain what factor of safety was maintained with a dosage
of 0.5 p.p.m. of available chlorine and 0.06-0.08 p.p.m. of ammonia. The
results are shown in Diagram VIII. The percentage of samples of treated
water showing _B. coli_ in 50 c.cms. was calculated from the results of
the examination of 4-7 samples daily.
The results showed that it was possible to reduce the chlorine dosage to
0.25 p.p.m. with 0.06 p.p.m. of ammonia without adversely affecting the
bacteriological purity of the tap supply and fully confirmed the
experimental results previously obtained.
The lowest ratio of available chlorine to ammonia used during this test
was approximately 4:1. This is the ratio indicated by a consideration of
the theory of the reaction, and not 2:1 as was formerly stated
(Race[4]). If bleach is represented as Ca(OCl)_{2}, the equation
Ca(OCl)_{2} + 2NH_{3} = 2NH_{2}Cl + Ca(OH)_{2}
would indicate a ratio of 2:1; but only one molecule of Ca(OCl)_{2} is
produced from two molecules of bleach and the theoretical ratio is
therefore 4:1 (142:34),
2CaOCl_{2} = CaCl_{2} + Ca(OCl)_{2} and Ca(OCl)_{2} + 2NH_{3} =
Cl = 142 34
= 2NH_{2}Cl + Ca(OH)_{2}.
The chlorine to ammonia ratio is very important because of its influence
on the economics of the process (_vide_ p. 124).
[Illustration: DIAGRAM VIII
CHLORAMINE TREATMENT, OTTAWA]
All the laboratory and works results that have been obtained in Ottawa
indicate the importance of an adequate contact period. The superiority
of chloramine over other processes is due to the non-absorption of the
germicidal agent and to obtain the same degree of efficiency the contact
period must be increased as the concentration is decreased. For this
reason the best results will be obtained by chlorinating at the entrance
to reservoirs or under other conditions that will ensure several hours
contact. At Ottawa the capacity of the pipes connecting the pumping
station (point of chlorination) and the distribution mains provides a
contact period of one and a quarter hours but even better results would
be obtained if the contact period were increased.
Public-domain text, read in full here on John Shaqi.
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