Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
In all combustion there is destruction or decomposition of the pure
air in which the combustion takes place, and the body burned increases
in weight exactly in proportion to the quantity of air destroyed or
decomposed.
FOURTH PHENOMENON
In all combustion the body burned changes to an acid by the addition
of the substance which has increased its weight: thus, for example,
if sulphur is burned under a receiver the product of the combustion is
vitriolic acid; if phosphorus be burned the product is phosphoric acid;
if a carboniferous substance, the product is fixed air, otherwise known
as acid of lime (carbonic acid, etc.).
(Note: I would remark in passing that the number of acids is infinitely
greater than has been supposed.)
The calcination of metals is subject to exactly the same laws, and it
is with very great reason that Mr. Macquer has treated it as a slow
combustion; thus, 1°, in all metallic combustion there is a liberating
of fire matter (_matière du feu_); 2°, veritable calcination can
take place only in pure air; 3°, there is a combination of the air with
the substance calcined, but with this difference, that in place of
forming an acid with it there results from it a particular combination
known as metallic calx.
This is not the place to point out the analogy which exists between the
respiration of animals, combustion and calcination; I shall return to
that in the sequel to this memoir.
These different phenomena of the calcination of metals and of
combustion are explained in a very happy manner by Stahl’s hypothesis;
but it is necessary with him to suppose the existence of fire matter
(_matière du feu_) or of fixed phlogiston in the metals, in
sulphur and in all bodies which he regards as combustibles; yet if the
partisans of Stahl’s doctrine are asked to prove the existence of fire
matter in combustible bodies, they fall necessarily into a vicious
circle and are obliged to reply that combustible bodies contain fire
matter because they burn, and that they burn because they contain fire
matter. It is easy to see that in the last analysis this is explaining
combustion by combustion.
The existence of fire matter, or phlogiston, in metals, in sulphur,
etc., is then really only an hypothesis, a supposition which, once
admitted, explains, it is true, some of the phenomena of calcination
and combustion; but if I show that these very phenomena may be
explained in quite as natural a way by the opposite hypothesis, that
is to say, without supposing the existence of either fire matter or
phlogiston in the substances called combustible, Stahl’s system will be
shaken to its foundations.
Public-domain text, read in full here on John Shaqi.
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