Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
“I will for the present satisfy myself with simply inquiring whether
it necessarily follows from this experiment that we must renounce
entirely the received theory of caloric, according to which it is
regarded as a substance which enters into combination with bodies, or
whether this result cannot be explained in a satisfactory manner by
applying to the case in question those laws of nature in accordance
with which the operations of heat are manifested under other
conditions.
“If the evolution of heat be regarded as a consequence of the decrease
of volume caused by the pressure, then not only the metallic powder,
but also all the rest of the brass cylinder must have contributed,
though not in an equal manner, to this evolution, by the powerful
expansive effort of that portion which experienced the greatest
pressure, and consequently acquired the greatest temperature, without
being able to assume the dimensions proper to this same temperature on
account of the less heated and less expanded parts; consequently there
must have arisen, necessarily, a certain condensation of the metal
in respect of its natural dimensions, which condensation gradually
decreased from the point where the pressure was greatest to the
surface. We may suppose that this operation took place in a similar
manner in all parts of the cylinder.
“As a consequence of this decrease of volume, an amount of caloric was
given out equal to that which would have caused a similar increase
of volume, on the supposition, that is, that the specific heat of
the metal does not change through this range of the scale of the
thermometer, and that the expansions are equal; and this, considering
the range of temperatures and the consequent expansions, is probably
not far from the truth. The entire amount of heat disengaged would
have raised the cylinder to about 180° of Reaumur’s scale; and if
the expansion of brass by heat is equal to that of iron, which has
been found to be 1-75000 for each degree of the thermometer, the 180
degrees would have caused an expansion of 18-75000 in each direction,
and the decrease of volume must have brought about the same degree of
heat if we suppose that the pressure stood in equal relation to this
expansion.
“Now there is a change, and sometimes a very considerable one, wrought
in the specific gravity of a metal, by percussion, by the action of
a fly-wheel, or by the compression of a wire-drawing machine. It
appears, for example, that the specific gravity of platina and of
iron, on being forged, is thus increased by a twentieth part.
“Hence it appears that the experiment of Count Rumford is far from
explaining satisfactorily a property which is well known, and called
in question by no one.
Public-domain text, read in full here on John Shaqi.
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