Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
“It is easy, it is true, to arrange side by side in an imposing manner
the phenomena of heat; if, however, you were to say to one who has
little or no knowledge of chemical speculations, ‘Count Rumford’s
cylinder has, in the course of two hours, by means of a violent
friction, afforded all the heat required to dissolve in water, without
changing its temperature, 15 kilogrammes of ice, or as much as 2
hectogrammes (6-1/2 ounces) of oxygen would require [_sic_] in
its combination with phosphorus,’ I do not know at which of these
phenomena he would be most astonished.
“The slight changes which can take place in the amount of combined
caloric have so inconsiderable an influence on the capacity for work
of the caloric within the narrow limits of the thermometric scale,
that it cannot be computed. Moreover, we have not, as yet, adequate
data for determining the nature of the changes in this respect which
take place in a solid body in consequence of the particular condition
of condensation into which it has been brought by means of certain
mechanical force, and by degrees of heat differing greatly from each
other.
“Besides, Rumford, in the experiment to determine the specific heat
of the filings of bell-metal thus obtained, heated them to the
temperature of boiling water. But this extremely elastic heat would
very naturally as soon as left to itself, and especially during the
operation just mentioned, resume that state of expansion and that
capacity for heat which is proper to it at a given temperature, so
that the effect of the pressure to which it has been subjected partly
disappears again, just as a piece of metal which has been hammered
resumes its natural properties on being annealed.”
In reply to these remarks, I will call to mind what follows.
1st. The discovery which I made, that no considerable change had
taken place in the specific heat of the metallic dust produced by the
friction, led me in no way to the supposition that the heat excited
in the experiment could not come from the caloric set free. I only
found that the source of this heat was inexhaustible. To explain this
phenomenon, which has never yet been explained, is the point now in
question, and I do not see how it can be explained except by giving up
altogether the hypothesis adopted in regard to caloric.
2d. If we actually suppose (and it is far from having been proved)
that the simple pressing together of a metal is sufficient to expel
the caloric contained in it; still the explanation of such a natural
phenomenon would be advanced little or none; for since the action of
the force which causes the pressure is continuous, the condensation
of the metal brought about by this force would in a short time reach
its maximum; and if really in this operation ever so much caloric had
been disengaged from the metal, still it would very soon disperse. The
rubbing surfaces, on the contrary, continue to give forth heat, and
that always to the same amount.
Public-domain text, read in full here on John Shaqi.
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