Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
_Avogadro, who continued the researches of Dalton and Gay-Lussac,
was born in Turin, Italy, June 9, 1776. In 1796, after receiving the
doctor’s degree in law from the University of Turin, he was employed
by the government for the following ten years. He began his work in
science in 1806 and three years later was made professor of physics at
Vercelli. In 1811 he announced his famous law. According to Merz, since
the time of Boyle “it had been known that equal volumes of different
gases under equal pressure change their volumes equally if the
pressure is varied equally, and it was also known that equal volumes
of different gases under equal pressure change their volumes equally
with equal rise of temperature. These facts suggested to Avogadro, and
almost simultaneously to Ampère, the very simple assumption that this
is owing to the fact that equal volumes of different gases contain an
equal number of the smallest independent particles of matter. This is
Avogadro’s celebrated hypothesis. It was the first step in the direct
physical verification of the atomic view of matter.”_
_In 1820 Avogadro became professor of physics at Turin University,
where he remained for many years. He died July 9, 1856._
THE MOLECULES IN GASES PROPORTIONAL TO THE VOLUMES[27]
I.
M. Gay-Lussac has shown in an interesting Memoir (_Mémoires de la
Société d’Arcueil_, Tome II.) that gases always unite in a very
simple proportion by volume, and that when the result of the union is a
gas, its volume also is very simply related to those of its components.
But the quantitative proportions of substances in compounds seem only
to depend on the relative number of molecules which combine, and on the
number of composite molecules which result. It must then be admitted
that very simple relations also exist between the volumes of gaseous
substances and the numbers of simple or compound molecules which form
them. The first hypothesis to present itself in this connection, and
apparently even the only admissible one, is the supposition that the
number of integral molecules in any gases is always the same for equal
volumes, or always proportional to the volumes. Indeed, if we were
to suppose that the number of molecules contained in a given volume
were different for different gases, it would scarcely be possible
to conceive that the law regulating the distance of molecules could
give in all cases relations so simple as those which the facts just
detailed compel us to acknowledge between the volume and the number
of molecules. On the other hand, it is very well conceivable that
the molecules of gases being at such a distance that their mutual
attraction cannot be exercised, their varying attraction for caloric
may be limited to condensing a greater or smaller quantity around
them, without the atmosphere formed by this fluid having any greater
extent in the one case than in the other, and, consequently, without
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