Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
the distance between the molecules varying; or, in other words, without
the number of molecules contained in a given volume being different.
Dalton, it is true, has proposed a hypothesis directly opposed to
this, namely, that the quantity of caloric is always the same for the
molecules of all bodies whatsoever in the gaseous state, and that the
greater or less attraction for caloric only results in producing a
greater or less condensation of this quantity around the molecules,
and thus varying the distance between the molecules themselves. But
in our present ignorance of the manner in which this attraction of
the molecules for caloric is exerted, there is nothing to decide
us _a priori_ in favour of the one of these hypotheses rather
than the other; and we should rather be inclined to adopt a neutral
hypothesis, which would make the distance between the molecules and
the quantities of caloric vary according to unknown laws, were it not
that the hypothesis we have just proposed is based on that simplicity
of relation between the volumes of gases on combination, which would
appear to be otherwise inexplicable.
Setting out from this hypothesis, it is apparent that we have the means
of determining very easily the relative masses of the molecules of
substances obtainable in the gaseous state, and the relative number
of these molecules in compounds; for the ratios of the masses of the
molecules are then the same as those of the densities of the different
gases at equal temperature and pressure, and the relative number of
molecules in a compound is given at once by the ratio of the volumes
of the gases that form it. For example, since the numbers 1.10359 and
0.07321 express the densities of the two gases oxygen and hydrogen
compared to that of atmospheric air as unity, and the ratio of the two
numbers consequently represents the ratio between the masses of equal
volumes of these two gases, it will also represent on our hypothesis
the ratio of the masses of their molecules. Thus the mass of the
molecule of oxygen will be about 15 times that of the molecule of
hydrogen, or, more exactly, as 15.074 to 1. In the same way the mass
of the molecule of nitrogen will be to that of hydrogen as 0.96913 to
0.07321, that is, as 13, or more exactly 13.238, to 1. On the other
hand, since we know that the ratio of the volumes of hydrogen and
oxygen in the formation of water is 2 to 1, it follows that water
results from the union of each molecule of oxygen with two molecules of
hydrogen. Similarly, according to the proportions by volume established
by M. Gay-Lussac for the elements of ammonia, nitrous oxide, nitrous
gas, and nitric acid, ammonia will result from the union of one
molecule of nitrogen with three of hydrogen, nitrous oxide from one
molecule of oxygen with two of nitrogen, nitrous gas from one molecule
of nitrogen with one of oxygen, and nitric acid from one of nitrogen
with two of oxygen.
II.
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