Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
The alkali was apparently dry in this experiment; and it seemed
probable that the inflammable matter arose from its decomposition.
The residual potash was unaltered; it contained indeed a number of
dark grey metallic particles, but these proved to be derived from the
platina.
I tried several experiments on the electrization of potash rendered
fluid by heat, with the hopes of being able to collect the combustible
matter, but without success; and I only attained my object by employing
electricity as the common agent for fusion and decomposition.
Though potash, perfectly dried by ignition, is a non-conductor, yet it
is rendered a conductor by a very slight addition of moisture, which
does not perceptibly destroy its aggregation; and in this state it
readily fuses and decomposes by strong electrical powers.
A small piece of pure potash, which had been exposed for a few seconds
to the atmosphere, so as to give conducting power to the surface, was
placed upon an insulated disc of platina, connected with the negative
side of the battery of the power of 250 of 6 and 4, in a state of
intense activity; and a platina wire, communicating with the positive
side, was brought in contact with the upper surface of the alkali. The
whole apparatus was in the open atmosphere.
Under these circumstances a vivid action was soon observed to take
place. The potash began to fuse at both its points of electrization.
There was a violent effervescence at the upper surface; at the lower,
or negative surface, there was no liberation of elastic fluid; but
small globules having a high metallic lustre, and being precisely
similar in visible characters to quicksilver, appeared, some of which
burnt with explosion and bright flame, as soon as they were formed, and
others remained, and were merely tarnished, and finally covered by a
white film which formed on their surfaces.
These globules, numerous experiments soon showed to be the substance
I was in search of, and a peculiar inflammable principle the basis
of potash. I found that the platina was in no way connected with the
result, except as the medium for exhibiting the electrical powers of
decomposition; and a substance of the same kind was produced when
pieces of copper, silver, gold, plumbago, or even charcoal were
employed for completing the circuit.
The phenomenon was independent of the presence of air; I found that it
took place when the alkali was in the vacuum of an exhausted receiver.
The substance was likewise produced from potash fused by means of
a lamp, in glass tubes confined by mercury, and furnished with
hermetically inserted platina wires by which the electrical action
was transmitted. But this operation could not be carried on for any
considerable time; the glass was rapidly dissolved by the action of
the alkali, and this substance soon penetrated through the body of the
tube.
Public-domain text, read in full here on John Shaqi.
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