Classics of modern science : $b (Copernicus to Pasteur)
History
Classics of modern science : $b (Copernicus to Pasteur)
Science; Science -- History
Soda, when acted upon in the same manner as potash, exhibited an
analogous result; but the decomposition demanded greater intensity
of action in the batteries, or the alkali was required to be in much
thinner and smaller pieces. With the battery of 100 of 6 inches in full
activity I obtained good results from pieces of potash weighing from
40 to 70 grains, and of a thickness which made the distance of the
electrified metallic surfaces nearly a quarter of an inch; but with a
similar power it was impossible to produce the effects of decomposition
on pieces of soda of more than 15 or 20 grains in weight, and that only
when the distance between the wires was about 1/8 or 1/10 of an inch.
The substance produced from potash remained fluid at the temperature of
the atmosphere at the time of its production; that from soda, which was
fluid in the degree of heat of the alkali during its formation, became
solid on cooling, and appeared having the lustre of silver.
When the power of 250 was used, with a very high charge for the
decomposition of soda, the globules often burnt at the moment of their
formation, and sometimes violently exploded and separated into smaller
globules, which flew with great velocity through the air in a state of
vivid combustion, producing a beautiful effect of continued jets of
fire.
THEORY OF THE DECOMPOSITION OF THE FIXED ALKALIES; THEIR COMPOSITION
AND PRODUCTION
As in all decompositions of compound substances which I had previously
examined, at the same time that combustible bases were developed at
the negative surface in the electrical circuit, oxygen was produced,
and evolved or carried into combination at the positive surface, it
was reasonable to conclude that this substance was generated in a
similar manner by the electrical action upon the alkalies; and a number
of experiments made above mercury, with the apparatus for excluding
external air, proved that this was the case.
When solid potash, or soda in its conducting state, was included
in glass tubes furnished with electrified platina wires, the new
substances were generated at the negative surfaces; the gas given out
at the other surface proved by the most delicate examination to be pure
oxygen; and unless an excess of water was present, no gas was evolved
from the negative surface.
In the synthetical experiments, a perfect coincidence likewise will be
found.
I mentioned that the metallic lustre of the substance from potash
immediately became destroyed in the atmosphere, and that a white crust
formed upon it. This crust I soon found to be pure potash, which
immediately deliquesced, and new quantities were formed, which in their
turn attracted moisture from the atmosphere till the whole globule
disappeared, and assumed the form of a saturated solution of potash.
Public-domain text, read in full here on John Shaqi.
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