The verification of a chemical theory necessitates investigations for
which supplies of the requisite materials must be forthcoming. Inasmuch as
the very materials wanted were separated from coal-tar and purified on a
large scale for manufacturing purposes, the science was not long kept
waiting. The laborious series of operations which the chemist working on a
laboratory scale had to go through in order to obtain raw materials, could
be dispensed with when products which were at one time regarded as rare
curiosities became available by the hundredweight. It is perhaps not too
much to say that the advancement of chemical theory in the direction
started by Kekule has been accelerated by a century owing to the
circumstance that coal-tar products have become the property of the
technologist. In other words, we might have had to wait till 1965 to reach
our present state of knowledge concerning the theory of benzenoid
compounds if the coal-tar industry had not been in existence. And this is
not the only way in which the industry has helped the science, for in the
course of manufacture many new compounds and many new chemical
transformations have been incidentally discovered, which have thrown great
light on chemical theory. From the higher standpoint of pure science, the
industry has therefore deservedly won a most exalted position.
With respect to the value of the coal-tar dyes as tinctorial agents, there
is a certain amount of misconception which it is desirable to remove.
There is a widely-spread idea that these colours are fugitive--that they
rub off, that they fade on exposure to light, that they wash out, and, in
short, that they are in every way inferior to the old wood or vegetable
dyes. These charges are unfounded. One of the best refutations is, that
two of the oldest and fastest of natural colouring-matters, viz. alizarin
and indigo, are coal-tar products. There are some coal-tar dyes which are
not fast to light, and there are many vegetable dyes which are equally
fugitive. If there are natural colouring-matters which are fast and which
are aesthetically orthodox, these are rivalled by tar-products which fulfil
the same conditions. Such dyes as aniline black, alizarin blue, anthracene
brown, tartrazine, some of the azo-reds and naphthol green resist the
influence of light as well as, if not better than, any natural
colouring-matter. The artificial yellow dyes are as a whole faster than
the natural yellows. There are at the present time some three hundred
coal-tar colouring-matters made, and about one-tenth of that number of
natural dyes are in use. Of the latter only ten--let us say 33 per
cent.--are really fast. Of the artificial dyes, thirty are extremely fast,
and thirty fast enough for all practical requirements, so that the fast
natural colours have been largely outnumbered by the artificial ones. If
Nature has been beaten, however, this has been rendered possible only by
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