taking advantage of Nature's own resources--by studying the chemical
properties of atoms, and giving scope to the play of the internal forces
which they inherently possess--
"Yet Nature is made better by no mean,
But Nature makes that mean: so, o'er that art,
Which, you say, adds to Nature, is an art
That Nature makes."
The story told in this chapter is chronologically summarized below--
1820. Naphthalene discovered in coal-tar by Garden.
1832. Anthracene discovered in coal-tar by Dumas and Laurent.
1834. Phenol discovered in coal-tar by Runge.
1842. Picric acid prepared from phenol by Laurent; manufactured in
Manchester in 1862.
1845. Benzidine discovered by Zinin.
1859. Corallin and aurin discovered by Kolbe and Schmitt and by Persoz;
leading to manufacture from oxalic acid and phenol.
1860. Synthesis of salicylic acid by Kolbe.
1864. Manchester yellow discovered by Martius, leading to manufacture of
alpha-naphthylamine and then to alpha-naphthol.
1867. Magdala red discovered by Schiendl.
1868. Synthesis of alizarin by Graebe and Liebermann, leading to the
utilization of anthracene, caustic soda, potassium chlorate and
bichromate, and calling into existence the manufacture of fuming
sulphuric acid.
1870. Gallein, the first of the phthaleins, discovered by A. v. Baeyer,
followed in 1871 by coerulein, and in 1874 by the eosin dyes
(Caro). These discoveries necessitated the manufacture of phthalic
acid and resorcinol.
1873. Orthochromatic photography discovered by Vogel.
1876. Azo-dyes from the naphthols introduced by Roussin and Poirrier and
Witt, leading to the manufacture of the naphthols, sulphanilic
acid, &c.
1877. Preparation of quinone from aniline by Nietzki, utilized in
photography in 1880 for manufacture of hydroquinone.
1878. Disulpho-acids of beta-naphthol introduced by Meister, Lucius, and
Bruening, leading to azo-dyes from aniline, toluidine, xylidine,
and cumidine.
1879. Acid naphthol yellow introduced by Caro.
" Biebrich scarlet, the first secondary azo-colour, introduced by
Nietzki.
" Nitroso-sulpho acid of beta-naphthol discovered by the writer;
followed in 1883 by naphthol green (O. Hoffmann), and in 1889 by
eikonogen (Andresen).
" Beta-naphthol violet, the first of the oxazines, discovered by the
writer; followed in 1881 by gallocyanin.
" Coal-tar saccharin discovered by Fahlberg; manufacture made
practicable in 1884.
1880. Synthesis of indigo by A. v. Baeyer.
" Quinoline synthesised by Skraup's process.
1881. Kairine introduced by O. Fischer, the first artificial febrifuge.
" Indophenol discovered by Koechlin and Witt.
" Azo-dyes from new sulpho-acid of beta-naphthol introduced by Bayer
& Co.
Public-domain text, read in full here on John Shaqi.
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