While the electrician is pushing forward with rapid strides, the chemist
is also moving onwards, and every year witnesses the discovery of new tar
products, or the utilization of constituents which were formerly of little
or no value. Thus if the cost of generating and distributing electricity
is being lowered, on the other hand the value of coal tar is likely to go
on advancing, and it would be rash to predict which will come out
triumphant in the end. But even if electricity were to gain the day it
would be worth while to distil coal at the pit's mouth for the sake of the
by-products, and there is, moreover, the tar from the coke ovens to fall
back upon--a source which even before the use of coal-gas the wise Bishop
of Llandaff advised us not to neglect.
CHAPTER II.
The nature of the products obtained by the destructive distillation of
coal varies according to the temperature of distillation, and the age or
degree of carbonization of the coal. The watery liquor obtained by the dry
distillation of wood is acid, and contains among other things acetic acid,
which is sometimes prepared in this way, and from its origin is
occasionally spoken of as "wood vinegar." The older the wood, the more
complete its degree of conversion into coal, and the smaller the quantity
of oxygen it contains, the more alkaline does the watery liquid become.
Thus the gas-liquor is distinctly alkaline, and contains a considerable
quantity of ammonia, besides other volatile bases. The uses of ammonia are
manifold, and nearly our whole supply of this valuable substance is now
derived from gas-liquor. The presence of ammonia in this liquor is
accounted for when it is known that this compound is a gas composed of
nitrogen and hydrogen. It has already been explained that coal contains
from one to two per cent. of nitrogen, and during the process of
distillation about one-fifth of this nitrogen is converted into ammonia,
the remainder being converted partly into other bases, while a small
quantity remains in the coke.
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