The process of purification is thus far one of fractional distillation
combined with chemical washing. In fact, all the processes of purification
to which these oils are submitted are essentially of the same character.
The principle of fractional distillation has already been explained
sufficiently for our present purpose. The process of washing a liquid may
appear mysterious to the uninitiated, but in principle it is extremely
simple. If we pour some water into a bottle, and then add some liquid
which does not mix with the water--say paraffin oil--the two liquids form
distinct layers, the one floating on the other. On shaking the bottle so
as to mix the contents, the two liquids form a homogeneous mixture at
first, but on standing for a short time separation into two layers again
takes place. Now if there was present in the paraffin oil some substance
soluble in the oil, but more soluble in water, such as alcohol, we should
by the operation described wash the alcohol out of the oil, and when the
liquids separated into layers after agitation the watery layer would
contain the alcohol. By drawing off the oil or the water the former would
then be obtained free from alcohol--it would have been "washed." This
operation is precisely what the manufacturer does on a large scale with
the coal-tar oils. These oils contain certain impurities of which some are
of an acid character and dissolve in alkalies, while others are basic and
dissolve in acid. The oil is therefore agitated in a suitable vessel
provided with mechanical stirring gear with an aqueous solution of caustic
soda, and after separation into layers the alkaline solution retaining the
acid impurities is drawn off. Then the oil may be washed with water in the
same way to remove the lingering traces of alkali, and then with
acid--sulphuric acid or oil of vitriol--which dissolves out basic
impurities and certain hydrocarbons not belonging to the benzene series
which it is desirable to get rid of. A final washing with water removes
any acid that may be retained by the oil.
Public-domain text, read in full here on John Shaqi.
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