philosophers from the time of Newton downwards, and foremost among these
must be ranked the late James Prescott Joule, who was the first to measure
accurately the exact amount of work corresponding to a given quantity of
heat.
In measuring heat (as distinguished from temperature) it is customary to
take as a unit the quantity necessary to raise a given weight of water
from one specified temperature to another. In measuring work, it is
customary to take as a unit the amount necessary to raise a certain weight
at a specified place to a certain height against the force of gravity at
that place. Joule's unit of heat is the quantity necessary to raise one
pound of water from 60 deg. to 61 deg. F., and his unit of work is the foot-pound,
_i.e._ the quantity necessary to raise a weight of one pound to a height
of one foot. Now the quantitative relationship between heat and work
measured by Joule is expressed by saying that the mechanical equivalent of
heat is about 772 foot-pounds, which means that the quantity of heat that
would raise one pound of water 1 deg. F. would, if converted into work, be
capable of raising a one-pound weight to a height of 772 feet, or a weight
of 772 lbs. to a height of one foot.
This mechanical equivalent ought to tell us exactly how much power is
obtainable from a certain weight of coal if we measure the quantity of
heat given out when it is completely burnt. Thus an average Lancashire
coal is said to have a calorific power of 13,890, which means that 1 lb.
of such coal on complete combustion would raise 13,890 lbs. of water
through a temperature of 1 deg. F., if we could collect all the heat generated
and apply it to this purpose. But if we express this quantity of heat in
its mechanical equivalent, and suppose that we could get the corresponding
quantity of work out of our pound of coal, we should be grievously
mistaken. For in the first place, we could not collect all the heat given
out, because a great deal is communicated to the products of combustion by
which it is absorbed, and locked up in a form that renders it incapable of
measurement by our thermometers. In the next place, if we make an
allowance for the quantity of heat which thus disappears, even then the
corrected calorific power converted into its mechanical equivalent would
not express the quantity of work practically obtainable from the coal.
Public-domain text, read in full here on John Shaqi.
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