=Chromic Acid=, now usually known as chromium-trioxide—CrO_{3}—is found
in beautiful red needles, which are slightly deliquescent. According
to the present accepted theory, water containing such crystals in
solution contains the true chromic acid, H_{2}CrO_{4}, which cannot be
produced as crystals. Both the crystals and a concentrated solution
in water give up with facility a part of their oxygen, sometimes with
explosions accompanied by the appearance of fire, and green chromium
oxide, now called sesquioxide, Cr_{2}O_{3}, is formed. Bichromates
of alkalies act in a similar manner, but in a lesser degree. If, for
instance, a few drops of sulphuric acid be added to a solution of
potassium bichromate, and then a little alcohol, or, instead of that,
a piece of sugar be added and moderate heat applied, the solution
will be violently agitated, its yellow-red colour will disappear,
the bichromate be decomposed, and chromium oxide be formed, which,
combining with the sulphuric acid, forms a solution of a violet green
colour. If a sufficient quantity of sulphuric acid be present, the
chromium sulphate and the potassium sulphate combine, forming chrome
alum crystals, octahedron in form, similar to those of ordinary alum,
but of a beautiful dark violet colour. The same are used in both the
carbon and collotype processes. Bichromate of ammonium is easily
decomposed by fire by heating it in a dry state. It will be understood
that in consequence of the decomposition, or rather reduction, of
chromic acid by organic matter, the latter is also decomposed and
oxidised in a corresponding degree. The agent producing this effect may
be either heat or light, or both together; but of special interest to
the collotypist is the action of light upon different combinations of
chromic acid, in the shape of alkali bichromates in conjunction with
organic matters.
=Glue or Gelatine=, in a solution containing about five per cent.
of one of the bichromates spread upon glass plates, and exposed to
light, will, where exposed, become dark brown, at the same time become
insoluble in water, and also lose its power of absorbing the same.
According to the researches of Dr. Eder, this brown substance consists
of chromium chromate and unaltered gelatine. The oxidised portion of
the latter remains soluble and may be entirely removed by treating with
warm water. During the exposure to light formic acid is undoubtedly
formed. Ammonium bichromate, with gelatine, is in the dry state much
more sensitive than the potassium salt; it also decomposes more readily
when heated in the gelatine solution, a matter which must not be lost
sight of in the preparation of the collotype plate.
=Isinglass=—a tolerably pure glutin. In conjunction with the
bichromates it presents the same characteristics as gelatine.
Public-domain text, read in full here on John Shaqi.
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