Common Minerals and RocksCrosby, William O. (William Otis)
Science
Common Minerals and Rocks
Crosby, William O. (William Otis)
Geology -- Study and teaching
But what water cannot do alone is accomplished very readily when the
water is aided by decaying organic matter, which is always hungry for
oxygen, being, in the language of the chemist, a powerful reducing
agent. The soil, in most places, has a superficial stratum of vegetable
mould or half-decayed vegetation. The rainwater percolates through this
and dissolves more or less of the organic matter, which is thus carried
down into the sand and clay beneath and brought in contact with the
ferric oxide, from which it takes a certain proportion of oxygen,
reducing the ferric to the ferrous oxide. At the same time the
vegetation is burned up by the oxygen thus obtained, forming carbon
dioxide, which immediately combines with the ferrous oxide, forming
carbonate of iron, which, being soluble under these conditions, is
carried along by the water as it gradually finds its way by subterranean
drainage to the bottom of the valley and emerges in a swamp or marsh.
Here one of two things will happen: If the marsh contains little or no
decaying vegetation, then as soon as the ferrous carbonate brought down
from the hills is exposed to the air it is decomposed, the carbon
dioxide escapes, and the iron, taking on oxygen from the air, returns to
its original ferric condition; and being then quite insoluble, it is
deposited as a loose, porous, earthy mass, commonly known as
bog-iron-ore, which becomes gradually more solid and finally even
crystalline through the subsequent action of heat and pressure. When
first deposited, the ferric oxide is combined with water or hydrated,
and is then known as limonite (specimen No. 12); at a later period the
water is expelled, and we call the ore hematite (specimen No. 13); and
at a still later age it loses part of its oxygen, becomes magnetic and
more crystalline, and is then known as magnetite (specimen No. 14). Thus
it is seen that the iron-ores, as we pass from bog-limonite to
magnetite, form a natural series similar to and parallel with that
afforded by the coals as we pass from peat to graphite.
If the drainage from the hills is into a marsh containing an abundance
of decaying vegetation, _i.e._, if peat is forming there, the ferrous
carbonate, in the presence of the more greedy organic matter, will be
unable to obtain oxygen from the air; and as the evaporation of the
water goes on, it will sooner or later become saturated with this salt,
and the latter will be deposited. Here we find an explanation of a fact
often observed by geologists, viz., that the carbonate iron-ores are
usually associated with beds of coal.
The formation of the iron-ores, like that of the coals and bitumens, is
a slow process; and the ores, like the coals, etc., will be pure only
where there is a complete absence of mechanical sediment, a condition
that is realized most nearly in marshes.
Public-domain text, read in full here on John Shaqi.
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