Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Phosphorus is eminently combustible; it melts and takes fire at the
temperature of one hundred degrees, and absorbs in its combustion nearly
once and a half its own weight of oxygen.
CAROLINE.
What! will a pound of phosphorus consume a pound and half of oxygen?
MRS. B.
So it appears from accurate experiments. I can show you with what
violence it combines with oxygen, by burning some of it in that gas. We
must manage the experiment in the same manner as we did the combustion
of sulphur. You see I am obliged to cut this little bit of phosphorus
under water, otherwise there would be danger of its taking fire by the
heat of my fingers. I now put into the receiver, and kindle it by means
of a hot wire.
EMILY.
What a blaze! I can hardly look at it. I never saw any thing so
brilliant. Does it not hurt your eyes, Caroline?
CAROLINE.
Yes; but still I cannot help looking at it. A prodigious quantity of
oxygen must indeed be absorbed, when so much light and caloric are
disengaged!
MRS. B.
In the combustion of a pound of phosphorus, a sufficient quantity of
caloric is set free to melt upwards of a hundred pounds of ice; this has
been computed by direct experiments with the calorimeter.
EMILY.
And is the result of this combustion, like that of sulphur, an acid?
MRS. B.
Yes; phosphoric acid. And had we duly proportioned the phosphorus and
the oxygen, they would have been completely converted into phosphoric
acid, weighing together, in this new state, exactly the sum of their
weights separately. The water would have ascended into the receiver, on
account of the vacuum formed, and would have filled it entirely. In this
case, as in the combustion of sulphur, the acid vapour formed is
absorbed and condensed in the water of the receiver. But when this
combustion is performed without any water or moisture being present, the
acid then appears in the form of concrete whitish flakes, which are,
however, extremely ready to melt upon the least admission of moisture.
EMILY.
Does phosphorus, in burning in atmospherical air, produce, like sulphur,
a weaker sort of the same acid?
MRS. B.
No: for it burns in atmospherical air, nearly at the same temperature as
in pure oxygen gas; and it is in both cases so strongly disposed to
combine with the oxygen, that the combustion is perfect, and the product
similar; only in atmospherical air, being less rapidly supplied with
oxygen, the process is performed in a slower manner.
CAROLINE.
But is there no method of acidifying phosphorus in a slighter manner, so
as to form _phosphorus_ acid?
MRS. B.
Yes, there is. When simply exposed to the atmosphere, phosphorus
undergoes a kind of slow combustion at any temperature above zero.
EMILY.
But is not the process in this case rather an oxydation than a
combustion? For if the oxygen is too slowly absorbed for a sensible
quantity of light and heat to be disengaged, it is not a true
combustion.
MRS. B.
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