Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
The case is not as you suppose: a faint light is emitted which is very
discernible in the dark; but the heat evolved is not sufficiently strong
to be sensible: a whitish vapour arises from this combustion, which,
uniting with water, condenses into liquid phosphorus acid.
CAROLINE.
Is it not very singular that phosphorus should burn at so low a
temperature in atmospherical air, whilst it does not burn in pure oxygen
without the application of heat?
MRS. B.
So it at first appears. But this circumstance seems to be owing to the
nitrogen gas of the atmosphere. This gas dissolves small particles of
phosphorus, which being thus minutely divided and diffused in the
atmospherical air, combines with the oxygen, and undergoes this slow
combustion. But the same effect does not take place in oxygen gas,
because it is not capable of dissolving phosphorus; it is therefore
necessary, in this case, that heat should be applied to effect that
division of particles, which, in the former instance, is produced by the
nitrogen.
EMILY.
I have seen letters written with phosphorus, which are invisible by
day-light, but may be read in the dark by their own light. They look as
if they were written with fire; yet they do not seem to burn.
MRS. B.
But they do really burn; for it is by their slow combustion that the
light is emitted; and phosphorus acid is the result of this combustion.
Phosphorus is sometimes used as a test to estimate the purity of
atmospherical air. For this purpose, it is burnt in a graduated tube,
called an _Eudiometer_ (PLATE XI. fig. 2.), and from the quantity of air
which the phosphorus absorbs, the proportion of oxygen in the air
examined is deduced; for the phosphorus will absorb all the oxygen, and
the nitrogen alone will remain.
EMILY.
And the more oxygen is contained in the atmosphere, the purer,
I suppose, it is esteemed?
MRS. B.
Certainly. Phosphorus, when melted, combines with a great variety of
substances. With sulphur it forms a compound so extremely combustible,
that it immediately takes fire on coming in contact with the air. It is
with this composition that phosphoric matches are prepared, which kindle
as soon as they are taken out of their case and are exposed to the air.
EMILY.
I have a box of these curious matches; but I have observed, that in very
cold weather, they will not take fire without being previously rubbed.
MRS. B.
By rubbing them you raise their temperature; for, you know, friction is
one of the means of extricating heat.
EMILY.
Will phosphorus combine with hydrogen gas, as sulphur does?
MRS. B.
Yes; and the compound gas which results from this combination has a
smell still more fetid than the sulphuretted hydrogen; it resembles that
of garlic.
Public-domain text, read in full here on John Shaqi.
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