Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Soda 8 Sulphuric Acid
|
| _Quies-_
|
| _cent_
|
_Result_ _Result_
Nitrat 7 _Divellent Attractions_ 6} 13 Sulphat
of Soda of Lime
|
|
| _Attrac-_
|
| _tions_
|
Nitric Acid 4 Lime
--
12
_Original Compound_
Nitrat of Lime.
We here suppose that we are to decompose sulphat of soda; that is, to
separate the acid from the alkali; if, for this purpose, we add some
lime, in order to make it combine with the acid, we shall fail in our
attempt, because the soda and the sulphuric acid attract each other by a
force which is superior, and (by way of supposition) is represented by
the number 8; while the lime tends to unite with this acid by an
affinity equal only to the number 6. It is plain, therefore, that the
sulphat of soda will not be decomposed, since a force equal to 8 cannot
be overcome by a force equal only to 6.
CAROLINE.
So far, this appears very clear.
MRS. B.
If, on the other hand, we endeavour to decompose this salt by nitric
acid, which tends to combine with soda, we shall be equally
unsuccessful, as nitric acid tends to unite with the alkali by a force
equal only to 7.
In neither of these cases of simple elective attraction, therefore, can
we accomplish our purpose. But let us previously combine together the
lime and nitric acid, so as to form a nitrat of lime, a compound salt,
the constituents of which are united by a power equal to 4. If then we
present this compound to the sulphat of soda, a decomposition will
ensue, because the sum of the forces which tend to preserve the two
salts in their actual state is not equal to that of the forces which
tend to decompose them, and to form new combinations. The nitric acid,
therefore, will combine with the soda, and the sulphuric acid with the
lime.
CAROLINE.
I understand you now very well. This double effect takes place because
the numbers 8 and 4, which represent the degrees of attraction of the
constituents of the two original salts, make a sum less than the numbers
7 and 6, which represent the degrees of attraction of the two new
compounds that will in consequence be formed.
MRS. B.
Precisely so.
CAROLINE.
But what is the meaning of _quiescent_ and _divellent_ forces, which are
written in the diagram?
MRS. B.
Quiescent forces are those which tend to preserve compounds in a state
of rest, or such as they actually are: divellent forces, those which
tend to destroy that state of combination, and to form new compounds.
Public-domain text, read in full here on John Shaqi.
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