Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
These are the principal circumstances relative to the doctrine of
chemical attractions, which have been laid down as rules by modern
chemists; a few others might be mentioned respecting the same theory,
but of less importance, and such as would take us too far from our plan.
I should, however, not omit to mention that Mr. Berthollet, a celebrated
French chemist, has questioned the uniform operation of elective
attraction, and has advanced the opinion, that, in chemical
combinations, the changes which take place depend not only upon the
affinities, but also, in some degree, on the respective quantities of
the substances concerned, on the heat applied during the process, and
some other circumstances.
CAROLINE.
In that case, I suppose, there would hardly be two compounds exactly
similar, though composed of the same materials?
MRS. B.
On the contrary, it is found that a remarkable uniformity prevails, as
to proportions, between the ingredients of bodies of similar
composition. Thus water, as you may recollect to have seen in a former
conversation, is composed of two volumes of hydrogen gas to one of
oxygen, and this is always found to be precisely the proportion of its
constituents, from whatever source the water be derived. The same
uniformity prevails with regard to the various salts; the acid and
alkali, in each kind of salt, being always found to combine in the same
proportions. Sometimes, it is true, the same acid, and the same alkali,
are capable of making two distinct kinds of salts; but in all these
cases it is found that one of the salts contains just twice, or in some
instances, thrice as much acid, or alkali, as the other.
EMILY.
If the proportions in which bodies combine are so constant and so well
defined, how can Mr. Berthollet’s remark be reconciled with this uniform
system of combination?
MRS. B.
Great as that philosopher’s authority is in chemistry, it is now
generally supposed that his doubts on this subject were in a great
degree groundless, and that the exceptions he has observed in the laws
of definite proportions, have been only apparent, and may be accounted
for consistently with those laws.
CAROLINE.
Pray, Mrs. B., can you decompose a salt by means of electricity, in the
same way as we decompose water?
MRS. B.
Undoubtedly; and I am glad this question occurred to you, because it
gives me an opportunity of showing you some very interesting experiments
on the subject.
If we dissolve a quantity, however small, of any salt in a glass of
water, and if we plunge into it the extremities of the wires which
proceed from the two ends of the Voltaic battery, the salt will be
gradually decomposed, the acid being attracted by the positive, and the
alkali by the negative wire.
EMILY.
But how can you render that decomposition perceptible?
MRS. B.
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