Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Is it not in this case the air of the room, which being warmer than the
marble, melts the ice?
MRS. B.
The air certainly acts on the surface which is exposed to it, but the
table melts that part with which it is in contact.
CAROLINE.
But why does caloric tend to an equilibrium? It cannot be on the same
principle as other fluids, since it has no weight?
MRS. B.
Very true, Caroline, that is an excellent objection. You might also,
with some propriety, object to the term _equilibrium_ being applied to a
body that is without weight; but I know of no expression that would
explain my meaning so well. You must consider it, however, in a
figurative rather than a literal sense; its strict meaning is an _equal
diffusion_. We cannot, indeed, well say by what power it diffuses itself
equally, though it is not surprising that it should go from the parts
which have the most to those which have the least. This subject is best
explained by a theory suggested by Professor Prevost of Geneva, which is
now, I believe, generally adopted.
According to this theory, caloric is composed of particles perfectly
separate from each other, every one of which moves with a rapid velocity
in a certain direction. These directions vary as much as imagination can
conceive, the result of which is, that there are rays or lines of these
particles moving with immense velocity in every possible direction.
Caloric is thus universally diffused, so that when any portion of space
happens to be in the neighbourhood of another, which contains more
caloric, the colder portion receives a quantity of calorific rays from
the latter, sufficient to restore an equilibrium of temperature. This
radiation does not only take place in free space, but extends also to
bodies of every kind. Thus you may suppose all bodies whatever
constantly radiating caloric: those that are of the same temperature
give out and absorb equal quantities, so that no variation of
temperature is produced in them; but when one body contains more free
caloric than another, the exchange is always in favour of the colder
body, until an equilibrium is effected; this you found to be the case
when the marble table cooled your hand, and again when it melted the
ice.
CAROLINE.
This reciprocal radiation surprises me extremely; I thought, from what
you first said, that the hotter bodies alone emitted rays of caloric
which were absorbed by the colder; for it seems unnatural that a hot
body should receive any caloric from a cold one, even though it should
return a greater quantity.
MRS. B.
It may at first appear so, but it is no more extraordinary than that a
candle should send forth rays of light to the sun, which, you know, must
necessarily happen.
CAROLINE.
Well, Mrs. B--, I believe that I must give up the point. But I wish I
could _see_ these rays of caloric; I should then have greater faith in
them.
MRS. B.
Public-domain text, read in full here on John Shaqi.
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