Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
Call it insensible caloric, and the difficulty will appear much less
formidable. It is indeed a sort of contradiction to call it heat, when
it is so situated as to be incapable of producing that sensation. Yet
this modification of caloric is commonly called SPECIFIC HEAT.
CAROLINE.
But it certainly would have been more correct to have called it
_specific caloric_.
EMILY.
I do not understand how the term _specific_ applies to this modification
of caloric?
MRS. B.
It expresses the relative quantity of caloric which different _species_
of bodies of the same weight and temperature are capable of containing.
This modification is also frequently called _heat of capacity_, a term
perhaps preferable, as it explains better its own meaning.
You now understand, I suppose, why the milk and chalk required a longer
portion of time than the lead to raise their temperature to that of the
oven?
EMILY.
Yes: the milk and chalk having a greater capacity for caloric than the
lead, a greater proportion of that fluid became insensible in those
bodies: and the more slowly, therefore, their temperature was raised.
CAROLINE.
But might not this difference proceed from the different conducting
powers of heat in these three bodies, since that which is the best
conductor must necessarily attain the temperature of the oven first?
MRS. B.
Very well observed, Caroline. This objection would be insurmountable, if
we could not, by reversing the experiment, prove that the milk, the
chalk, and the lead, actually absorbed different quantities of caloric,
and we know that if the different time they took in heating, proceeded
merely from their different conducting powers, they would each have
acquired an equal quantity of caloric.
CAROLINE.
Certainly. But how can you reverse this experiment?
MRS. B.
It may be done by cooling the several bodies to the same degree in an
apparatus adapted to receive and measure the caloric which they give
out. Thus, if you plunge them into three equal quantities of water, each
at the same temperature, you will be able to judge of the relative
quantity of caloric which the three bodies contained, by that, which, in
cooling, they communicated to their respective portions of water: for
the same quantity of caloric which they each absorbed to raise their
temperature, will abandon them in lowering it; and on examining the
three vessels of water, you will find the one in which you immersed the
lead to be the least heated; that which held the chalk will be the next;
and that which contained the milk will be heated the most of all. The
celebrated Lavoisier has invented a machine to estimate, upon this
principle, the specific heat of bodies in a more perfect manner; but I
cannot explain it to you, till you are acquainted with the next
modification of caloric.
EMILY.
The more dense a body is, I suppose, the less is its capacity for
caloric?
MRS. B.
Public-domain text, read in full here on John Shaqi.
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