Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
This is not always the case with bodies of different nature; iron, for
instance, contains more specific heat than tin, though it is more dense.
This seems to show that specific heat does hot merely depend upon the
interstices between the particles; but, probably, also upon some
peculiar constitution of the bodies which we do not comprehend.
EMILY.
But, Mrs. B., it would appear to me more proper to compare bodies by
_measure_, rather than by _weight_, in order to estimate their specific
heat. Why, for instance, should we not compare _pints_ of milk, of
chalk, and of lead, rather than _pounds_ of those substances; for equal
weights may be composed of very different quantities?
MRS. B.
You are mistaken, my dear; equal weight must contain equal quantities of
matter; and when we wish to know what is the relative quantity of
caloric, which substances of various kinds are capable of containing
under the same temperature, we must compare equal weights, and not equal
bulks of those substances. Bodies of the same weight may undoubtedly be
of very different dimensions; but that does not change their real
quantity of matter. A pound of feathers does not contain one atom more
than a pound of lead.
CAROLINE.
I have another difficulty to propose. It appears to me, that if the
temperature of the three bodies in the oven did not rise equally, they
would never reach the same degree; the lead would always keep its
advantage over the chalk and milk, and would perhaps be boiling before
the others had attained the temperature of the oven. I think you might
as well say that, in the course of time, you and I should be of the same
age?
MRS. B.
Your comparison is not correct, Caroline. As soon as the lead reached
the temperature of the oven, it would remain stationary; for it would
then give out as much heat as it would receive. You should recollect
that the exchange of radiating heat, between two bodies of equal
temperature, is equal: it would be impossible, therefore, for the lead
to accumulate heat after having attained the temperature of the oven;
and that of the chalk and milk therefore would ultimately arrive at the
same standard. Now I fear that this will not hold good with respect to
our ages, and that, as long as I live, I shall never cease to keep my
advantage over you.
EMILY.
I think that I have found a comparison for specific heat, which is very
applicable. Suppose that two men of equal weight and bulk, but who
required different quantities of food to satisfy their appetites, sit
down to dinner, both equally hungry; the one would consume a much
greater quantity of provisions than the other, in order to be equally
satisfied.
MRS. B.
Yes, that is very fair; for the quantity of food necessary to satisfy
their respective appetites, varies in the same manner as the quantity of
caloric requisite to raise equally the temperature of different bodies.
EMILY.
The thermometer, then, affords no indication of the specific heat of
bodies?
MRS. B.
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