Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by ExperimentsMarcet, Mrs. (Jane Haldimand)
Science
Conversations on Chemistry, V. 1-2: In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments
Marcet, Mrs. (Jane Haldimand)
Chemistry
None at all: no more than satiety is a test of the quantity of food
eaten. The thermometer, as I have repeatedly said, can be affected only
by free caloric, which alone raises the temperature of bodies.
But there is another mode of proving the existence of specific heat,
which affords a very satisfactory illustration of that modification.
This, however, I did not enlarge upon before, as I thought it might
appear to you rather complicated. --If you mix two fluids of different
temperatures, let us say the one at 50 degrees, and the other at 100
degrees, of what temperature do you suppose the mixture will be?
CAROLINE.
It will be no doubt the medium between the two, that is to say, 75
degrees.
MRS. B.
That will be the case if the two bodies happen to have the same capacity
for caloric; but if not, a different result will be obtained. Thus, for
instance, if you mix together a pound of mercury, heated at 50 degrees,
and a pound of water heated at 100 degrees, the temperature of the
mixture, instead of being 75 degrees, will be 80 degrees; so that the
water will have lost only 12 degrees, whilst the mercury will have
gained 38 degrees; from which you will conclude that the capacity of
mercury for heat is less than that of water.
CAROLINE.
I wonder that mercury should have so little specific heat. Did we not
see it was a much better conductor of heat than water?
MRS. B.
And it is precisely on that account that its specific heat is less. For
since the conductive power of bodies depends, as we have observed
before, on their readiness to receive heat and part with it, it is
natural to expect that those bodies which are the worst conductors
should absorb the most caloric before they are disposed to part with it
to other bodies. But let us now proceed to LATENT HEAT.
CAROLINE.
And pray what kind of heat is that?
MRS. B.
It is another modification of combined caloric, which is so analogous to
specific heat, that most chemists make no distinction between them; but
Mr. Pictet, in his Essay on Fire, has so clearly discriminated them,
that I am induced to adopt his view of the subject. We therefore call
_latent heat_ that portion of insensible caloric which is employed in
changing the state of bodies; that is to say, in converting solids into
liquids, or liquids; into vapour. When a body changes its state from
solid to liquid, or from liquid to vapour, its expansion occasions a
sudden and considerable increase of capacity for heat, in consequence of
which it immediately absorbs a quantity of caloric, which becomes fixed
in the body which it has transformed; and, as it is perfectly concealed
from our senses, it has obtained the name of _latent_ heat.
CAROLINE.
I think it would be much more correct to call this modification latent
caloric instead of latent heat, since it does not excite the sensation
of heat.
MRS. B.
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