Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Prop._ Pure solid albumen (unaltered by heat) is nearly colourless,
inodorous, and tasteless; scarcely soluble in water, but readily so in
water, containing an exceedingly small quantity of caustic soda or potash,
and in a strong solution of nitrate of potassium. When dried by a gentle
heat it shrinks into a translucent horny mass; and when exposed to a
sufficient temperature, yields the usual ammoniacal odour and products of
animal matter. Its solution (as white of egg) is solidified or coagulated
by a heat of from 145° to 165° Fahr., forming a white, opaque mass; when
very dilute, on boiling (only) it separates in fine light flocks. When
thus coagulated, it is insoluble in water at a less temperature than 302°
Fahr. (Wöhler and Vögel), unless alkalised. Ordinary solutions of albumen
give precipitates with sulphuric, hydrochloric, nitric, and metaphosphoric
acids, with tannin and astringent solutions, and with most of the metallic
salts; but are not affected by either acetic acid or tribasic (common)
phosphoric acid. Alcohol, in quantity, also precipitates albumen. Strong
oil of vitriol turns it black in the cold, but on applying a gentle heat,
a gorgeous, red-coloured liquid is produced. Strong hydrochloric acid
gives a deep violet-blue solution. White of egg or serum exposed in a thin
stratum to the air, dries up into a pale, yellow, gum-like substance, and
in this state may be kept for any length of time, retaining its property
of redissolving when immersed in slightly warm water.
_Tests._——1. Both heat and alcohol (or strong spirit) coagulate it:——2. A
solution of perchloride of mercury dropped into a fluid containing
albumen occasions a white precipitate:——3. Subacetate of lead acts in the
same way. Either of the last two will render turbid a solution containing
only the 1-2000th part of fresh white of egg, or the 1-10,000th part of
dry albumen:——4. Tannin and tincture of galls give yellow, pitchy
precipitates:——5. If dry caustic potash or soda be triturated with either
liquid or solid albumen, ammoniacal fumes are evolved, and the mixture on
calcination yields ferrocyanide of potassium:——6. Its coagulability by
heat, and its incoagulability by acetic acid, distinguish it from casein.
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