Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
presence of which would vitiate the results of the trial. To allow the
piston to be withdrawn without any shock, or the danger of dividing the
column abruptly, the rod attached to it is made hollow throughout. In
using it the operator applies the ball of his forefinger to the top of the
piston-rod (_E_), in order to create a vacuum as he raises it; and then
withdraws it, to readmit the air when he thrusts it down or removes it
from the tube. The excess of liquid (if any) in the pipette is then run
off until its upper surface is exactly level with the zero (0) of the
scale, at 25° C., to which it is raised by immersion in a water bath of
that temperature, as observed by the thermometer; which is done by very
cautiously turning the rod which depresses the valve. The whole apparatus
is now again immersed in the water bath; and, held by the upper portion of
the plate, kept in gentle motion with the hand, until the temperature
rises to exactly 50° C., when the coefficient of expansion is obtained,
and hence also the proportion of alcohol——the scale of the instrument
being so graduated, from actual experiments previously made upon mixtures
of known composition, as to give, at once, the per-centage of alcohol by
VOLUME (nearly).[14]
[Footnote 14: ‘Comptes Rendus,’ xvii, 418.]
[Illustration]
_e._ From the TENSION of the VAPOUR:——Geissler’s ALCOHOLOMETER. This
method, for which we are indebted to M. Geissler, of Bonn, depends on the
measurement of the tension or elastic force of the vapour of the liquid,
as indicated by the height to which it raises a small column of mercury.
The spirit, wine, or other liquor, of which it is desired to ascertain the
strength, is put into the little flask (_a_), which, when completely
filled, is screwed on to the curved glass-tube which contains the
mercurial column (which is inverted for the purpose), and is closed by the
stop-cock (_b_). The instrument (see _engr._) is then placed erect, and
the flask and lower part of the tube immersed in a water bath, as in the
previous method. The number, on the graduated scale of the instrument
corresponding to the height of the mercury, at the boiling point of the
liquor under examination, gives the per-centage of alcohol by VOLUME
(nearly).
This method furnishes approximative results with great facility and
expedition; and, with proper care, these do not vary more than 1/3 to 1/2
of 1%, from those obtained by distillation. We find, that by having the
diameter of the part of the tube at which the surface of the mercury is
acted on by the vapour a little larger than that of the longer limb, and
by previously abstracting the air from the sample, as in Silbermann’s
method, or even by agitation and exposure in an open vessel, the two may
be made to correspond almost exactly.
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