Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_f._ From the DIFFERENCE between the sp. gr. BEFORE and AFTER
ebullitiom:——Taberié’s method and ŒNOMETER. The sp. gr. of the sample is
first accurately determined by any of the usual methods. It is next
carefully evaporated, in an open vessel, to one half its volume. The
residuum, when cold, is made up with pure water to exactly its original
measure at its original temperature, and the sp. gr. again ascertained.
The difference between the two being due to the spirit originally present,
furnishes the means of calculating a new sp. gr., from which the
per-centage richness of the sample may be obtained by mere inspection of
the Tables. The observed sp. gr. is the true one, whenever the liquor,
after ebullition and restoration to its original volume, has the same sp.
gr. as water (_i. e._, 1·000), at 60° Fahr. Taberié employs a peculiar
instrument, which he calls an œnometer; but its use is not essential to
his method of alcoholometry. The results are, of course, only
approximative, though sufficient for all ordinary purposes. Prof. Mulder,
however, says that he prefers it to any of the previous methods; and that
the results, with care, are almost as accurate as those obtained by
distillation.
_g._ By means of CARBONATE OF POTASH:——
_g. a._ (Brande’s Method.) The liquor for trial is poured into a long,
narrow glass tube (graduated centesimally), until the vessel is
half-filled, and, after the solution of about 12% or 15% of a strong
solution of subacetate of lead, or a little finely powdered litharge, is
agitated until the colour is entirely, or nearly removed. Anhydrous
carbonate of potash, in powder, is next added, until it sinks undissolved,
even after prolonged agitation of the liquid. The whole is now allowed to
repose for a short time, when the alcohol is seen floating on the top of
the aqueous portion of the liquid in a well-marked stratum. Its quantity,
read off by means of the graduations of the tube, and doubled, gives the
per-centage richness of the sample in alcohol, by volume.
This process answers well with cordials, wines, and the stronger ales; but
with very weak liquors it is not to be relied on. The whole operation may
be performed in two to five minutes, and (with these exceptions) furnishes
very reliable approximative results. In most cases the decolouring part of
the process may be omitted. The alcohol thus separated has a sp. gr. of
from ·8061 to ·8118, and contains 3% or 4% of water; but for ordinary
purposes it may be regarded as pure alcohol.
4. Alcoholometry of MINUTE QUANTITIES of liquid. When only a few drops, or
a quantity too small for the application of the preceding methods, can be
obtained, an organic analysis may be had recourse to, and the quantity of
absolute alcohol calculated from that of the resulting carbonic anhydride
and water; care being previously taken to free the sample from other
volatile bodies, if it contains any of them.
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