Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
“In the one process we proceed as follows——We take about one part by
weight of anthraquinone and about three parts by weight of sulphuric acid
of about specific gravity of 1·488, and introduce the same into a retort,
which may be made of glass, or porcelain, or of any other material not
easily acted upon by sulphuric acid, and the contents are then to be
heated up to about 260° Centigrade, and the temperature is maintained
until the mixture is found no longer to contain any appreciable quantity
of unaltered anthraquinone. The completion of this operation may be
ascertained or tested by withdrawing a small portion of the product from
time to time, and continuing the operation at the high temperature until
such product upon being diluted with water is found to form a
substantially perfect solution, thereby indicating that the anthraquinone
has become either entirely or in greater part converted into the desired
product. The products thus obtained are then allowed to cool, and are
diluted with water; carbonate of lime is then added in order to neutralise
and remove the excess of sulphuric acid contained in the solution; the
mixture is then filtered, and to the filtrate carbonate of potash, or
carbonate of soda, by preference in solution, is to be added until
carbonate of lime is no longer precipitated; the mixture is then filtered,
and the clear solution is evaporated to dryness, by which means the potash
or soda salts of the sulpho-acids of anthraquinone are obtained, and which
are to be treated in the following manner:——We take about one part by
weight of this product, and from two to three parts by weight of solid
caustic, soda, or potash; water may be added or not, but by preference we
add as much water as is necessary to dissolve the alkali after admixture;
we heat the whole in a suitable vessel, and the heating operation is
continued at a temperature of from about 180° to 260° Centigrade, for
about one hour, or until a portion of the mixture is found upon
withdrawing and testing it to give a solution in water, which being
acidulated with an acid, for example, sulphuric acid, will give a copious
precipitate of the colouring matters. The heating operation having been
found to have been continued for a sufficient time, the resulting products
are then dissolved in water, and we either filter or decant the solution
of the same, from which we precipitate the colouring matters or artificial
alizarin, by means of a mineral or organic acid, such, for example, as
sulphuric or acetic acid. The precipitated colouring matters thus obtained
are collected in a filter or otherwise, and after having been washed may
be employed for the purpose of dyeing and printing, either in the same way
as preparations of madder are now used or otherwise.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account