Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
“In carrying out our other process we proceed as follows:——We take about
one part by weight of anthracene and about four parts by weight of
sulphuric acid of specific gravity of about 1·848, and the mixture being
contained in a suitable vessel, is heated to a temperature of about 100°
Centigrade, and which temperature is to be maintained for the space of
about three hours; the temperature is then to be raised to about 150°
Centigrade, which temperature is to be maintained for about one hour, or
until a small portion of the product when submitted to the two subsequent
processes hereinafter described is found to produce the desired colouring
matters; we then allow the result obtained by this operation to cool, and
dilute it with water, by preference in the proportion of about three times
its weight. To the solution thus obtained we add for every part of
anthracene by weight which had been employed in the previous operations,
from about two to three parts by weight of peroxide of manganese,
preferring to employ an excess, and we boil the whole strongly for some
time, and in order fully to ensure the desired degree of oxidation the
mixture may be subsequently concentrated, and by preference be evaporated
to dryness, and the heat be continued until a small portion of the
oxidised product, when submitted to the subsequent processes hereinafter
described will produce the desired colouring matters. We then neutralise
and remove the sulphuric acid contained in this mixture, and at the same
time precipitate any oxides of manganese that may be held in solution, by
adding an excess of caustic lime, which we use by preference in the form
of milk of lime, and we add the same until the mixture has an alkaline
reaction. We then filter, and add to the filtrate carbonate of potash or
soda, until there is no further precipitation of carbonate of lime. The
solution is then filtered and evaporated to dryness, and we thus obtain
the potash or soda salts of what we call the sulpho-acids of
anthraquinone.
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