Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Test-acids_ may be very simply prepared by gradually diluting
concentrated sulphuric acid with water until it is reduced to the proper
strength; the dilution being made in a glass vessel containing a
‘hydrostatic bead’ exactly corresponding to the desired specific gravity
of the dilute acid. When the proper point is reached, and the mixture has
again acquired the normal temperature of 60° Fahr., the bead rises from
the bottom of the vessel, and floats about indifferently in the middle of
the liquid. The sp. gr. may then he carefully ascertained by means of an
hydrometer or a specific gravity bottle; after which the strength must be
accurately determined by means of a standard solution of either pure
anhydrous carbonate of soda or pure caustic soda. An acid of any given
strength or saturating power may also be prepared in the following
manner:——49 parts of commercial sulphuric acid (oil of vitriol), sp. gr.
1·825, contain nearly 40 parts or 1 equiv. of anhydrous sulphuric acid; if
we, therefore, wish to prepare a dilute acid containing in every 1000
grains weight, or measure, exactly 1 equiv. of hydrated sulphuric acid, we
have only to make 49 gr. of such acid up to 100 gr. weight or measure with
pure water. After it has recovered the proper temperature, its sp. gr., or
rather its saturating power, must be carefully tried, and, if necessary,
readjusted. As, however, it very often happens that the oil of vitriol
employed is not so strong as that above referred to, it is better first to
test its strength with pure anhydrous carbonate of soda, and to calculate
the quantity required by the Rule of Proportion. Every 53 gr. of the dry
carbonate are equal to 40 gr. of ‘dry sulphuric acid.’ Suppose we find the
oil of vitriol to contain only 72% of hydrated acid, then——
100 : 40 :: 72 : 55·55
or, instead of only 40 gr., fully 55-1/4 gr. will be required, which are
to be made up with water to 1000 gr., as before. Finally, the diluted acid
must be very carefully re-tested, and if found correct, at once put into a
well-stoppered bottle, and labelled, for use. Too much care cannot be
taken to ensure the test-liquid, whether for alkalies or acids, being of
the proper strength, of which the specific gravity alone is an
insufficient proof. In practice, so small a quantity only of test-acid as
that referred to above is, of course, seldom made; but as any larger
quantities are mere multiples of the smaller one, the necessary
proportions to be employed are easily calculated. The common plan is to
prepare one or more gallons or quantities of 10 lbs. each, and to preserve
the liquid in stoppered green glass ‘Winchester-quart bottles,’ so that it
may be always ready for use.
Although, as may be inferred from the text, sulphuric acid is generally
used as the standard acid, yet oxalic acid in pure crystals is recommended
by M. Mohr, and answers admirably, and is prepared and used exactly in the
same manner.
TABLE II.——_Alkalimetrical Equivalents._
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