Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Amylic alcohol._——Solanine (1061); digitalin sparingly soluble; morphine
(133); strychnine (122); veratrine, brucine, atropine, aconitine, and
picrotoxin, freely soluble.
_Benzol._——All the poisonous alkaloids, except solanine, are soluble in
benzol.
_Chloroform._——Solanine (50,000); morphine (6550); strychnine (8); the
rest freely soluble.
_Ether._——Solanine (9000); morphine (7725); strychnine (1400); aconitine
(777); brucine (440); veratrine (108); atropine, picrotoxin,[26] and
digitalin, very soluble.
[Footnote 26: Digitalin and picrotoxin, although not alkaloids, are
inserted in the above list, because they have a general similarity in
chemical properties to them; and for the convenience of the toxicologist.]
_Water_ (_cold_).——Strychnine (8333); veratrine (7860); morphine (4166);
aconitine (1783); solanine (1750); brucine (900); atropine (414);
picrotoxin (150); digitalin very soluble.
The principal Alkaloids and their Salts, in the state of powder, or with
‘conia’ and ‘nicotia,’ in the state of an oily looking liquid, may be thus
distinguished:——
1. _a._ The powder is treated with nitric acid:——It is coloured red;
probable presence of Brucia, Delphia, Morphia, or commercial Strychnia. If
the reddened acid becomes violet on the addition of ‘protochloride of
tin,’ it is BRUCIA; if it becomes black and carbonaceous, it is DELPHIA.
If the powder is fusible without decomposition, and strongly decomposes
iodic acid, it is MORPHIA; if it is not fusible without decomposition, and
does not decompose iodic acid, it is STRYCHNIA.
_b._ If instead of a red, the powder strikes a green colour with nitric
acid, it is SOLANIA; if it is insoluble in ‘ether,’ and not reddened by
‘nitric acid,’ it is EMETIA; if soluble in ether, not reddened by ‘nitric
acid,’ but melts and volatilises when heated, it is ATROPIA; if it is thus
affected by ether or nitric acid, but does not volatilise, it is VERATRIA.
(See 2, _below_.)
2. _a._ The powder, or (with ‘conia and nicotia’) concentrated liquor, is
treated with a drop or two of concentrated sulphuric acid:——A red colour
is produced; probable presence of Brucia, Nicotina, Salicine, or Veratria.
If the reddened mixture has at first a roseate hue, turning deep red on
the addition of nitric acid, it is BRUCIA; if the original substance
moistened with solution of potassa evolves the odour of tobacco, it
contains NICOTINE; if the red colour produced by the acid is permanent and
of an intense blood-hue, and the powder agglutinates into lumps like
resin, it is SALICINE; if the colour is at first yellowish, changing to
blood-red, and ultimately to crimson and violet, it is VERATRIA.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account