Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_b._ If instead of the substance being ‘reddened’ by strong sulphuric
acid, no particular action ensues in the cold, it contains either Conia or
Strychnia; if a small fragment of bichromate of potassa being now dropped
in, produces a rich violet colour, it is STRYCHNIA; if the original matter
on being heated, or treated with solution of potassa, evolves a
penetrating, disagreeable odour, somewhat analogous to that from
‘hemlock,’ or to a mixture of those from tobacco and mice, it is CONIA.
“_Reactions with ceroso-ceric oxide._ This oxide exhibits characteristic
colours with several alkaloids, especially with STRYCHNINE. When strong
sulphuric acid is poured upon strychnine, and then a small quantity of
ceroso-ceric oxide added, a fine blue colour is produced, similar to that
which strychnine exhibits with potassium bichromate, but much more
permanent. The blue colour gradually changes to cherry-red, and then
remains unaltered for several days. This reaction is capable of detecting
one part of strychnine in a million parts of liquid. BRUCINE similarly
treated acquires an orange-colour, gradually changing to yellow; MORPHINE,
olive-brown, finally brown; NARCOTINE, brown cherry red, finally wine-red;
CODEINE, olive-green, finally brown; QUININE, pale-yellow; CINCHONINE and
THEINE remain colourless; VERATRINE becomes reddish-brown; ATROPINE, dingy
yellowish-brown; SOLANINE, yellow at first, finally brownish; EMETINE,
brown; COLCHICINE, first green, then dirty brown; ANILINE, after a long
time, acquires a blue colour extending from the edges inwards; CONINE
becomes light-yellow. PIPERINE colours the sulphuric acid blood-red, and
is turned dark-brown, almost black by the cerium oxide” (Sonnenschein).
“_Reactions with picric acid._ This acid is a very good precipitant for
alkaloids, affording a very delicate test for many of them, and may
perhaps also serve for separating them one from another. The precipitation
takes place even in solutions containing a large excess of sulphuric
acid, and is sometimes complete. _Precipitated_ are, BRUCINE, STRYCHNINE,
VERATRINE, QUINIDINE, CINCHONINE, and most of the opium alkaloids; _not
precipitated_, MORPHINE, ATROPINE (English), PSEUDO-MORPHINE, CAFFEINE,
and all glucosides” (Hager).
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