Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_d._ From Bauxite. This mineral, occurring in some parts of Southern
France, in Calabria, near Belfast, and in other parts of Europe, consists
essentially (viz. 60 per cent.) of hydrate of alumina, more or less pure.
In order to prepare alums and sulphate of alumina from it, the mineral is
first disintegrated by being ignited with carbonate of soda, or with a
mixture of sulphate of soda and charcoal; in each case the lixiviation of
the ignited mass yields aluminate of soda, from which, by the processes
already described under “Cryolite,” alum, or sulphate of alumina, and soda
are prepared.
_e._ From blast-furnace slag. Lürmann recommends the slag to be decomposed
by means of hydrochloric (muriatic) acid. From the resulting solution of
chloride of aluminum the alumina is precipitated by carbonate of lime, any
dissolved silica being precipitated at the same time. The alumina is
dissolved in sulphuric acid, leaving the silica.
[Illustration]
_Prop._ Alum crystallises in regular octahedrons, often with truncated
edges and angles; (see _engr._); and sometimes in cubes, but only when
there is a deficiency of acid in its composition, with the alkali in
slight excess of the proper quantity. (Löwel.)[38] It is slightly
efflorescent in dry air: soluble in 18 parts of cold water, and in rather
less than its own weight of boiling water; tastes sweet, acidulous, and
very astringent; is styptic; and reddens litmus. When heated it melts,
loses its water of crystallisation, and becomes white and spongy (DRIED
ALUM); a strong heat, short of whiteness, decomposes it, with the
evolution of oxygen and a mixture of sulphuric and sulphurous anhydride;
calcined with carbonaceous matter it suffers decomposition, and furnishes
a pyrophoric residuum (HOMBERG’S PYRO′PHORUS). Ignited with alkaline
chlorides, hydrochloric acid is liberated; which also occurs when their
concentrated solutions are boiled together. Ammonia precipitates pure
hydrate of aluminum from potassium alum; but only a subsulphate from the
simple sulphate of alumina. Sp. gr. 1·724; but, when containing ammonia,
often so low as 1·710.
[Footnote 38: The ordinary alum, of commerce, consisting of large
crystalline masses, which do not present any regular geometrical form; but
by immersion in water for a few days, octahedral and rectangular forms are
developed on its surface. (Daniell.)]
_Tests, &c._ It is easily recognised by its crystalline form, its taste,
and by its complete solubility in water. Its aqueous solution gives a
white gelatinous precipitate soluble in excess; a platinum wire moistened
with the solution imparts a violet colour to the blowpipe flame; and
chloride of barium gives a white precipitate insoluble in nitric acid.
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