Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
=ALU′MEN= (-l′ōō-). [L.] Alum; the pharmacopœial name of alum. (See
_above_.)
=ALUMINIUM.= _Syn._ ALUMINUM (which _see_).
=ALUMINOUS.= In _mineralogy_, of, resembling, or containing aluminum. In
_chemistry_, containing or obtained from alum.
=ALUMINUM.= [Eng., Fr., L.] _Syn._ ALUMINIUM, Eng., Fr., L.; ALUMIUM, Ger.
A metallic radical or element very abundantly distributed, united with
silica. Discovered by M. Wöhler, who succeeded in obtaining it as a grey
metallic powder (A.D. 1827); and later (1845), under the form of globules
exhibiting the leading characteristics of the metal. In 1854, M. Dumas
announced to the ‘Academy of Sciences,’ that M. St. Clair Deville had
procured pure aluminum from clay, and exhibited several specimens of
considerable size and beauty. The result was a general impression that it
might be easily obtained in any quantity, and ultimately at a reasonable
price; expectations which have been only partly, though to a great extent
fulfilled, owing to the expense and trouble of the process,
notwithstanding recent improvements.
_Prep._ (M. Deville; A.D. 1854-59.)——A quantity of chloride of aluminum,
varying from 200 to 300 grammes (say from 6 to 10 oz.), is introduced into
a wide glass or porcelain tube, between two plugs of asbestos to retain it
in position, and a current of hydrogen (thoroughly dried by passing first
through concentrated sulphuric acid, and then through a tube containing
fused chloride of calcium) passed over it; a gentle heat being at the same
time applied to the part of the tube containing the chloride, to drive off
any free hydrochloric acid which might have been formed by the action of
the air upon it. A small porcelain boat, containing sodium, is now
introduced at the other extremity of the glass tube, which is then again
closed; and when the sodium is fused, the chloride is sufficiently heated
to cause its vapour to come into free contact with it. A powerful reaction
ensues, with the evolution of much heat, and this continues as long as any
undecomposed sodium remains to act on the passing vapour. The mass in the
boat, which is now a mixture of the double chloride of aluminum and
sodium, in which small globules of the newly reduced metal are suspended,
is allowed to cool in the hydrogen; after which it is treated with water,
to remove the soluble double chloride. The residuum, consisting of small
globules of aluminum, is, lastly, reduced to a solid button or mass, by
fusion, at a strong heat, under a layer of the fused double chloride of
aluminum and sodium.
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