Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
On a large scale two cast-iron cylinders are employed, instead of the
glass or porcelain tube just referred to; the anterior one of which
contains the chloride of aluminum, and the posterior one a tray holding
the sodium, of which 10 or 12 lbs. are commonly operated on at once. These
cylinders are united by means of a smaller intermediate one, filled with
clean scraps of iron, which serve to separate iron, free hydrochloric
acid, and chloride of sulphur, from the vapour of the chloride of
aluminum, as it passes through them. During the passage of the vapour of
the chloride this smaller cylinder, or tube, is kept heated to from 400°
to 600° Fahr.; but the two other cylinders are only very gently heated,
since the chloride is volatilised at a comparatively low temperature, and
the reaction between it and the fused sodium, when once commenced, usually
generates sufficient heat for the completion of the process.
Occasionally a mixture of the double chloride of aluminum and sodium, 40
parts; chloride of sodium 20 parts; fluor spar, 20 parts; each separately
dried, powdered, and then blended together; sodium, in small pieces, 7-1/2
to 8 parts, are used instead of the last.
It is likewise made from a mixture of cryolite and fused chloride of
potassium, of each, in powder, 5 parts; sodium, 2 parts; a cast-iron
crucible being employed; the resulting minute globules being collected and
fused to a button under a layer of the double chloride of aluminum and
sodium.
_Prop., &c._ Aluminum, when quite pure, closely approaches silver in
appearance, except in being rather less white and lustrous than that
metal. Ordinary specimens, called pure, have a slight bluish tint or
tin-white colour, with a perfect lustre, but far inferior to that of pure
silver. Sp. gr. 2·56, which by hammering may be raised to 2·67. It is both
ductile and malleable; fuses at a temperature between the melting-points
of zinc and silver; is not affected by either damp or dry air, or by
oxygen at ordinary temperatures, or by water whether cold or boiling; even
steam, at a red heat, is only slowly decomposed by it. It is not acted on
by nitric acid, however concentrated, unless boiling, and then very
slowly; nor by dilute sulphuric acid, sulphuretted hydrogen, and the
sulphides, or even the fused hydrates of the alkalies. It is, however,
readily dissolved by hydrochloric acid, with the evolution of hydrogen,
even in the cold; and by a concentrated mixture of nitric and sulphuric
acid. It is feebly magnetic, conducts electricity about eight times better
than iron, and is more electro-negative than zinc. Commercial specimens,
owing to the presence of iron and silicon, and often zinc, usually slowly
tarnish in damp air, and possess the other properties described above in a
somewhat diminished degree.
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