Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
In addition to what has been said above, it may be observed that, in
preparing aluminum, the chief care should be to avoid accidents or failure
by the employment of too high a temperature, and to avoid the product
being contaminated with other metals or with carbon. To ensure the purity
of the metal is a matter of the greatest difficulty, owing to the facility
with which foreign matters are taken up, during the process, from the
materials of which the apparatus is composed; and from the substances from
which it is prepared being seldom absolutely pure. Indeed, it is not too
much to assert that chemically pure aluminum has not yet been obtained;
and that even a very close approximation to it is of very rare occurrence.
Whenever a copper boat is used to hold the sodium, the product is always
contaminated with copper. Chloride of aluminum always contains some of the
chlorides of iron and silicon, both of which are volatile, and probably
takes up a further portion from the porcelain or earthenware used to form
the apparatus. Sodium also is seldom uncontaminated with carbon or some
compound of it; in which case, and likewise when it is not carefully freed
from the naphtha in which it has been preserved, the product always
contains carbon. The crucible, whether of porcelain or iron, in which the
final fusion is made, also contributes to contaminate the metal. Hence the
inferior whiteness and brilliancy of commercial specimens of aluminum; a
metal which, in its absolutely pure state, may be reasonably inferred to
be as superior in the above respects to silver as silver is to tin.
Commercial aluminum contains from 88 to 94 per cent. only of pure
aluminum, and from 1 to 4 per cent. of iron, 1/2 to 3 per cent. of
silicon, and from 1 to 6 per cent. of copper.
Aluminum salts are generally colourless, soluble, and crystallise with
difficulty, and are distinguished as follows:——
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