Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Tests._——1. Ammonia and the alkaline carbonates throw down a bulky white
precipitate (hydrate of aluminum) from solutions of its salts, which is
insoluble in excess of the precipitant.——2. Pure potassa and soda throw
down white gelatinous precipitates, freely soluble in excess of the
precipitant; from which the hydrate of aluminum is reprecipitated by
chloride of ammonium, even in the cold:——3. Phosphate of ammonium gives a
white precipitate——4. Iodide of potassium produces a white precipitate,
passing into a permanent yellow:——5. Sulphuretted hydrogen gives no
precipitate:——6. Sulphydrate of ammonium precipitates alumina from these
solutions:——7. Bisulphate of potassium, added to concentrated solutions,
gives a precipitate of octahedral crystals of alum:——8. At a red heat its
salts part with some of their acid; at a white heat, most of it, if not
all:——9. Aluminum compounds, ignited on charcoal before the blowpipe, and
afterwards moistened with a solution of nitrate of cobalt and again
strongly ignited, give an unfused mass, which, on cooling, appears blue by
day, and violet by candlelight; a test, however, which is inapplicable to
fusible compounds of aluminum, and such as are not free, or nearly free,
from other oxides.
=Aluminum, Acetate of.= _Syn._ ACETATE OF ALUMINA. _Prep._ Pure hydrate of
aluminum is digested, to saturation, in strong acetic acid, in the cold;
and the resulting solution, after being filtered or decanted, is either
evaporated by a very gentle heat to a gelatinous, semi-solid consistence
(its usual form), or is preserved in the liquid state. By spontaneous
evaporation it may be obtained in long, transparent crystals.
_Red liquor._ From alum, in powder, 4 parts; warm water, q. s. to
dissolve; acetate of lead, in powder, 3 parts; the solution and mixture
being effected by lengthened agitation in a tub or other wooden vessels,
and the clear liquid, after repose for a sufficient time, decanted or
drawn off from the sediment.
From alum, 2 parts; (dissolved in) warm water, q. s.; solution of
pyrolignite of lime (20° Baumé), 3 parts; as before, but allowing a longer
time for the subsidence of the precipitate, and taking more care in the
decantation than when acetate of lead is employed.
By decomposing a solution of crude sulphate of alumina with neutral or
monobasic acetate of lead.
_Prop._ Its characteristic property is the feeble affinity existing
between its acid and base, which, when it is used as a mordant, is
counterbalanced by that of the fibres of the cloth or yarn to which it is
applied. In other respects it resembles the other simple salts of alumina.
Public-domain text, read in full here on John Shaqi.
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