Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Ammonia, in a state of combination, is found, in variable quantities,
among the saline product of volcanoes, in sea and rain water, in
bituminous coal, in urine, in guano, and in the atmosphere, especially
that of large towns. The minute stellated crystals sometimes found on
dirty windows in London, and other populous cities, consist of sulphate of
ammonia. It is also found in clayey and peaty soils, and in minute
quantity in good air and water. (Brande; Fownes; Letheby.) In the free
state it exists in the juices of some plants, and in the living blood of
animals, and it is freely developed during the decomposition of azotised
vegetable substances, and during the putrefaction of animal matter.
[Illustration]
_Prep._ A mixture of fresh hydrate of lime with an equal weight of sal
ammoniac (both dry and in fine powder) is introduced into a glass flask or
retort, the beak of which communicates with one end of a U-shaped tube
filled with small fragments of recently burnt quick-lime, and from which
extends another glass tube, about 18 inches long, having its further end
bent up ready to be placed under a gas-jar, on the shelf of a mercurial
pneumatic trough. (See _engr._) The joints being all made air-tight by
collars of india rubber, heat is applied by means of a spirit-lamp, and as
soon as the air contained in the apparatus is expelled, the gas is
collected for use. It cannot be dried by means of chloride of calcium.
Powdered quick-lime may be substituted for the hydrate in the above
process; in which case the evolved gas is anhydrous, but a much greater
heat is then required for its liberation.
_Comp._ Ammonia is a compound of 3 volumes of hydrogen, and 1 vol. of
nitrogen, condensed into two volumes; and by weight of 82·35 parts of
nitrogen, 17·65 parts of hydrogen, or, in other words, of one atomic
weight of nitrogen and three of hydrogen, having the formula NH_{3}.
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