Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Prop._ Gaseous, colourless, invisible; highly pungent, acrid, irritating
and alkaline; irrespirable, unless very largely diluted with air;
extinguishes combustion; burns slowly in oxygen; sp. gr. 0·589; 100 cub.
inches weigh 18·26 gr. Under a pressure of 6·5 atmospheres, at 50° Fahr.,
it forms a transparent, colourless liquid of the sp. gr. 0·731; at 60°
Fahr. this liquid expanded into 1009 times its volume of ammoniacal gas;
at -40° Fahr., and the ordinary atmospheric pressure, it forms a subtle
colourless liquid, which at -103° Fahr. freezes into a white, translucent,
crystalline substance. (Faraday.) It is highly basic; all its salts are
either volatilised or decomposed at, or under, a red heat——those with a
volatile acid sublime unchanged——those with a fixed acid lose their
ammonia. It is decomposed into its elements by transmission through a
red-hot tube; and when in contact with metallic oxides or spongy platinum,
at the same temperature, the newly evolved hydrogen unites with the oxygen
of the oxide or of the atmosphere, forming water. Water at 50° Fahr.
absorbs 670 times its volume of this gas, and the solution has the sp. gr.
0·875. Its concentrated aqueous solution boils at 130°, and freezes at
-40° Fahr.
_Tests, &c._ Ammonia is recognised by——1. Its pungent odour:——2. By
turning vegetable blues green, and vegetable yellows brown; but which soon
regain their previous colours, especially on the application of heat:——3.
By producing dense white fumes when brought in contact with those of
hydrochloric acid:——4. By the Nessler test (see WATER, QUANTITATIVE AND
QUALITATIVE ANALYSIS OF):——5. If a saturated solution of arsenious acid is
mixed with a solution of nitrate of silver (strength 2%) a trace of
ammonia causes the formation of try-argentic arsenite:——6. Böttger says a
very delicate test for ammonia is afforded by an aqueous solution of
carbolic acid. On adding to a liquid containing the smallest quantity of
ammonia, or an ammoniacal salt, a few drops of this solution, and then a
small quantity of a filtered solution of chloride of lime, the liquid
becomes green, especially when warmed.
_Phys. eff., &c._ Inhaled, undiluted with air, it is an irritant poison,
producing spasms of the glottis, convulsions, and death; even when diluted
it acts as a powerful acrid, and local irritant; applied to the skin it
causes vesication. The use of the pungent odour of common ‘smelling
salts,’ in syncope, headache, &c., is well known. Largely diluted with
air, it has been recently highly extolled in chronic hoarseness, asthma,
&c.; and as an antidote to the fumes of bromine, chlorine, and hydrocyanic
acid. (Smee.)
_Ant., &c._ The vapour of acetic acid or common vinegar, freely inhaled.
It may be produced by sprinkling a little on a piece of hot iron, as a
heated shovel. If bronchial inflammation follows, it must be treated by
purgatives and a low diet; and, if severe, and the patient be plethoric or
robust, by venesection or cupping.
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