Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
3. Mallet’s Apparatus. This, which is employed in many of the large gas
works, is shown in vertical section in the accompanying woodcut. Steam is
forced into large receptacles, which are filled with gas water, by which
means the carbonate of ammonia is volatilised. When lime, as is sometimes
the case, is added, ammonia gas is evolved, and this being conveyed into
weak sulphuric acid, sulphate of ammonia is the result.
[Illustration]
The apparatus consists of two cylindrical boiler-plate vessels, A and B. A
is heated directly by the fire, and has a leaden tube, _c_, which dips
into the liquid contained in B, this vessel being so placed as to catch
the waste heat from the fire. _b_ and _e_ are man-holes; _a_ and _a′_ are
stirrers. By means of the tube _d_ the fluid from B can be run off into A.
Gas-water is poured into both vessels, and lime added; ammonia is
liberated, whilst carbonate of lime and sulphide of calcium are formed,
and these latter remain in the vessels after the volatilisation of the
ammonia. The vessel D is also filled with ammoniacal water, and when the
operation is in action this water, already warmed, is run by the aid of
the tube _h_ from D into B. E is a gas-water tank, from which D is filled
by means of _g_. The ammonia set free in A is, with the steam, conveyed by
the pipe _c_ into B, thence through _c′_ into the wash-vessel C, and
thence again through _c″_ into the first condenser, D. The partially
condensed vapour now passes into the condensing vessel F, the worm of
which is surrounded by cold water. The dilute ammonia is collected in G,
and forced by means of the pump (R) into C, from whence it is occasionally
removed by means of a syphon into either A or B. The non-condensed
ammoniacal gas is carried from G through a series of Wolfe’s bottles, the
first bottle (H) containing olive oil, with the object of retaining any
hydrocarbons that may be present in the gas; the bottle J contains caustic
soda-ley, in order to purify the ammonia and retain impurities; the bottle
K is half filled with distilled water. The ammoniacal gas having passed
through K, is conveyed to the large wooden tank (lined with lead) L,
filled with diluted sulphuric acid, if it is intended to prepare sulphate
of ammonia, or with water, if solution of ammonia be required. The vessel
L is placed in a tank of water; _i_ is a small pipe for introducing acid,
while the tube leading to M serves to carry off any unabsorbed ammonia, M
being likewise filled with acid.
4. By means of Rose’s apparatus, the ammoniacal gas-liquor mixed with one
third of slaked lime is heated in a boiler to a temperature of from 96° to
100°, the ammoniacal gas evolved being passed into hydrochloric acid, and
thence through charcoal into vessels containing from 120 to 150 litres of
water, which is converted into liquid ammonia of a sp. gr. 0·920.
5. In Lunge’s apparatus the gas-water is heated in a boiler, and the
liberated ammoniacal gas passed into sulphuric acid.
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