Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Uses, &c._ In the _arts_, chiefly in the coating and soldering of metals,
and the preparation of alloys; in dyeing; and in the manufacture of
ammonia-alum; also, in large quantities, to give a factitious pungency to
snuff. In _chemistry_, as a reagent; and, owing to the cold produced
during its solution, to form frigorific mixtures. In _medicine_ it is
chiefly used externally, as a stimulant and resolvent or discutient; and
occasionally, internally, as a diuretic, stimulant, resolvent, alterative,
tonic, &c., particularly in chronic inflammations of the mucous and serous
membranes, in chronic glandular and visceral enlargements and indurations,
and in amenorrhœa. In rather large doses, frequently repeated, it is said
to prove often highly beneficial in chronic enlargement and induration of
the prostate gland (M. René Vanoye); and also in other like
cases.——_Dose_, 5 to 20 gr., 3 or 4 times daily, either in powder or
solution, mixed with some demulcent; as a discutient or resolvent lotion,
1 to 1-1/2 oz., to 1/2 pint of water, either with or without 4 or 5 fl.
oz. of spirits or strong vinegar (often serviceable in chilblains); as a
weak lotion, or a collyrium or injection, 1 to 4 dr., to water, 1 pint. In
very large doses it is poisonous; the treatment is emetics and
mucilaginous or demulcent drinks.
_Concluding remarks, Patents, &c._ The methods already described are those
by which commercial hydrochlorate of ammonia is usually if not almost
entirely obtained; the various improvements or modifications, from time to
time introduced, affecting chiefly the minor details, and the form or size
of the apparatus and machinery employed, and not the general principles on
which the processes are based. One of the most important of these has for
its object the entire removal of the iron present in the crude salt, some
of which, if it be not removed before sublimation, is volatilised and
contaminates the ultimate product. To obviate this evil, Mr Brewer passes
a few bubbles of chlorine through the hot concentrated solution of the
salt, previous to its crystallisation; by which the protochloride of iron
is converted into the perchloride, which, being acted on by the ammonia
always present in the liquor, is precipitated as ferric hydrate, with the
formation of a small additional quantity of sal ammoniac. The only
precaution necessary is to avoid employing more chlorine gas than is
necessary to peroxidise the iron; as beyond this a portion of the
ammonia-salt itself is decomposed, with the evolution of nitrogen. The
temperature of the liquor is kept up, after the action of the chlorine,
until the whole of the brown flocculent oxide of iron has subsided, when
it is at once decanted or filtered into the crystallisers.
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