Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Atoms. Equiv. wt. Per cent.
Ammonia (NH_{3}) 1 17· 31·78
Hydrochloric acid (HCl) 1 36·5 68·22
--- ----- ------
Hydrochlorate of Ammonia (NH_{3}HCl) 1 53·5 100·
Or, according to the ‘ammonium-theory,’ of——
Atoms. Equiv. wt. Per cent.
Ammonium (NH_{4}) 1 18· 33·65
Chloride (Cl) 1 35·5 66·35
--- ----- ------
Chloride of Ammonium (NH_{4}Cl) 1 53·5 100·
_Prop. &c._ The sal ammoniac of commerce is found under the form of large
white hemispherical, cup-like cakes or masses (or in large fragments which
are sections of them), possessing a tough, fibrous, semi-crystalline
texture, and very difficult to powder. It is odourless, has a saline taste
somewhat sharp or acrid, and sublimes without either fusion or
decomposition. It slightly reddens litmus; dissolves in rather less than 3
parts of cold water, and in about 1 part of boiling water; is soluble in
alcohol; and when crystallised from water, under favorable circumstances,
forms distinct octahedra, or cubes, usually small and aggregated together
in rays or feathery masses. By slowly evaporating its aqueous solution, it
may be sometimes obtained in cakes an inch in thickness. It is anhydrous.
Sp. gr. 1·450.
_Pur._ It should give a colourless solution with water; wholly sublime
with heat; and neither chloride of barium, nor sulphuretted hydrogen,
should affect its solution. A solution, to which a few drops of nitric
acid have been added, should not yield a blue precipitate with
ferrocyanide of potassium. It often contains sesquichloride of iron, and
sometimes lead; both of which may be readily detected by the above tests.
Its complete volatility may be easily determined by heating, in the flame
of a candle, a small fragment held on the point of a knife.
_Tests._——1. It is known to be a salt of ammonium by its cooling
ammoniacal fumes when triturated with lime, or when moistened with caustic
potassa or soda:——2. It is shown to be a chloride by its solution
yielding, with nitrate of silver, a white curdy precipitate, insoluble in
boiling nitric acid, soluble in ammonia.
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