Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Prop._ Crystals, long, flattened, six-sided prisms; soluble in 2 parts of
cold, and 1 of boiling water; fuses, with loss of one atom of water, at
about 280° Fahr.; and is volatilised, with entire decomposition, at about
535°. Even its solution, by long boiling, becomes acid from loss of
ammonia. The anhydrous salt does not exist.
_Uses, &c._ Pure sulphate of ammonia is diuretic, aperient, resolvent, and
stimulant.——_Dose_, 10 to 30 gr. It is now seldom employed in medicine.
The crude sulphate is principally used in the preparation of sal ammoniac
and sesquicarbonate of ammonia, and for manure. “A mixture of 10% of this
sulphate with 20% of bone-dust, some gypsum, and farm-yard manure, forms a
very fertilising compost, applicable to a great variety of soils” (Ure);
and we may add——greatly superior to a very large portion of what is now so
commonly vended under the name of ‘guano.’
_Concluding remarks, Patents, &c._ The manufacture of sulphate of ammonia,
on the large scale, has been unavoidably explained in treating on the
salts of that base already noticed. All that is necessary is to saturate
with sulphuric acid the solution of ammonia, crude or otherwise, and
obtained in any manner; and then to evaporate the solution until the salt
crystallises out. At other times, however, instead of adding the acid to
the ammoniacal liquor, the latter, either at once, or after treatment with
lime, is submitted to distillation, and the evolved alkaline vapour is
passed into the acid (previously somewhat diluted), contained in a large
receiver or cistern, or a series of them; the salt being obtained from the
resulting solution in the usual manner. By re-solution and a second
crystallisation the sulphate is generally obtained sufficiently pure for
all commercial purposes; but when the salt is intended for use as manure,
or (unless very rough) for conversion into sal ammoniac, this need not be
had recourse to.
Among modifications and improvements, not previously noticed, may be
mentioned——
1. That of Dr Richardson (Patent dated Jan., 1850), who mixes SULPHATE OF
MAGNESIA with the crude ammoniacal liquor, and thus forms a double
sulphate of magnesia and ammonia, from which he obtains the SULPHATE OF
AMMONIA by sublimation.
2. That of Michiel (Patent dated April, 1850), who prepares sulphate of
ammonia by means of OXYSULPHATE OF LEAD obtained by roasting galena
(sulphide of lead), by exposing it in a crushed state and thin layers for
2 or 3 hours, to the heat of a reverberatory furnace. The resulting
mixture of sulphate and oxide of lead is reduced to the state of coarse
powder, and well worked up with the ammoniacal liquor, when SULPHATE OF
AMMONIA and sulphide and carbonate of lead are produced by the mutual
reaction of the elements present. The first is removed by treatment with
water; and the residuum serves for the manufacture of lead compounds, or
may be reduced to the metallic state by fusion in the usual manner.
Public-domain text, read in full here on John Shaqi.
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