Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
3. That of Mr Laming (Patent dated Aug., 1852), in which a stream of
SULPHUROUS ACID GAS is transmitted through the liquor containing the
ammonia, either in the free state or as carbonate, by which SULPHITE OF
AMMONIA is formed. This salt he oxidises, and thus converts into the
SULPHATE OF AMMONIA, by agitation and free exposure to the air.
Sulphate of ammonia, like the hydrochlorate, may also be obtained by
saturating stale urine with the acid, and subsequent evaporation and
crystallisation. See AMMONIA; AMMONIA, CARBONATES OF; AMMONIUM, CHLORIDE
OF, and MANURES, &c.
=Ammonium, Sulphide of (neutral).= (NH_{4})_{2}S. _Prep._ Saturate strong
solution of ammonia with pure sulphuretted hydrogen gas; then add a second
portion of solution of ammonia, equal to that first used, and preserve it
in a well-stoppered bottle.
=Ammonium, Sulphydrate of.= NH_{4}HS. _Syn._ SULPHIDE OF AMMONIUM,
HYDROSULPHIDE OF AMMONIUM, HYDROSULPHATE OF AMMONIA. _Prep._ By passing
sulphuretted hydrogen gas, to saturation, through a mixture composed of
strong solution of ammonia, 1 part, and distilled water, 4 parts.
_Props._ Prepared as above, it has a very fœtid odour. When pure it is
wholly volatilised by heat, and does not disturb a solution of sulphate of
magnesium. Mineral acids decompose it, with the evolution of sulphuretted
hydrogen. By keeping, it decomposes and acquires a yellow colour. This
yellow coloration does not, however, render it unfit for use as a reagent;
but it must be borne in mind that it will now deposit sulphur when mixed
with acids. In this state it proves valuable as a reagent to detect
hydrocyanic acid, and as a solvent to separate metallic sulphides thrown
down by sulphuretted hydrogen.
_Uses, &c._ It is principally employed by chemists as a reagent to
precipitate metals, to separate metallic sulphides, &c.; and by the
perfumers as a mordant in dyeing hair. In _medicine_ it has been used by
Cruickshank, Rollo, and others, to check the morbid appetite, and to
increase the action of the stomach and general tone of the system in
diabetes mellitus. It has also been used by Brauw, Gruithuisen, and
others, in old pulmonary and vesical catarrhs. It is a powerful sedative,
lessening the action of the circulatory system, causing nausea, vomiting,
vertigo, drowsiness, &c.——_Dose_, 3 to 6 drops, three or four times daily,
mixed with pure water, and instantly swallowed. In large doses it is
poisonous.
_Ant._ Very dilute solution of chlorine, or of chloride of lime or soda,
followed by a powerful emetic, or the stomach-pump. When the vapour has
been respired, free exposure to fresh air, with the head a little
elevated, and copious affusions of cold water, with moderate draughts of
brandy-and-water, and the use of the smelling-bottle (ammoniacal) should
be adopted. If need be, artificial respiration should be attempted, and
the air around the patient should be slightly impregnated with the fumes
of chlorine or chloride of lime.
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