Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
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Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
_Prop., &c._ All the neutral acetates, except those of molybdenum and
tungsten, are more or less soluble in water, several so much so as to be
uncrystallizable; many dissolve in alcohol; they suffer decomposition at a
dull red heat, and by distillation, at that temperature, yield acetone and
water, or acetone and acetic acid, and leave a carbonaceous residuum; at a
full red-heat, those of potassium, sodium, barium, strontium, calcium, and
magnesium, are converted into carbonates, whilst the other metallic
acetates leave behind the pure metal, or its oxide. The aqueous solutions
of the alkaline acetates soon turn mouldy and suffer decomposition. No
more of them should, therefore, be dissolved at once than is required for
immediate use.
_Char., tests, &c._ The acetates are known——1. By evolving fumes of acetic
acid, recognisable by its peculiar and characteristic odour, on the
addition of strong sulphuric acid:——2. By evolving the vapour of acetic
ether (known by its peculiar and agreeable odour) when heated with a
mixture of about equal parts of concentrated sulphuric acid and alcohol.
=AC′ETATED= (ăs′-). In _chemistry_ and _pharmacy_, combined or impregnated
with acetic acid or vinegar.
=ACE′TIC.= _Syn._ ACE′TICUS, L.; ACÉTIQUE, Fr. Of or relating to vinegar;
made with acetic acid, as perfumes, &c. (See _below_.)
=ACETIC ACID.= HC_{2}H_{3}O_{2}. _Syn._ PYROLIG′NEOUS ACID (_pure_); ACID
OF VINEGAR; ACIDUM ACE′TICUM, L.; ACIDE ACETIQUE, Fr.; ACIDO ACETICO, It.;
ESSIGSÄURE, Ger.; AZYNZUUR, Dut.; EISEL, Sax. When free from water it
crystallises on cooling, and is distinguished as——ACETIC HYDRATE,
HY′DRATED ACETIC ACID, MONOHY′DRATED A. A., GLA′CIAL A. A., MONOHYDRATED
A. A., ACE′TUM GLACIA′LE, ACIDUM ACE′TICUM G., L., &c. the sour principle
of vinegar.
_Var._ Commercial acetic acid is found under the form of the pure acid of
the chemist and pharmaceutist (glacial and dilute), and of vinegar, of
which there are several varieties, which are noticed under their
respective heads.
_Sources._ Fermented liquors; the vinegars of commerce; alcoholic liquors;
wood, from which it is obtained, as pyroligneous acid, by distillation;
the commercial acetates of soda, potassa, lime, lead, copper, &c. The pure
acetic acid of the chemist and of commerce is almost wholly obtained from
the acetates, either by the action of a strong acid, which seizes on the
base, setting the acid free; or, by dry distillation, in which the high
degree of heat employed separates the acetic acid from the base in the
form of vapour. It is also obtained by the oxidation of alcohol.
_Prep._ The following are the principal processes at present adopted to
obtain pure acetic acid:——
1. From the _Acetates_ in the moist way:——
_a._ From ACETATE OF SODA:——
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