Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Acetic acid is produced either by the partial dehydrogenation and
subsequent oxidation of bodies containing its elements, or by their
destructive distillation. The first is effected——by their exposure, in a
finely divided state, to the action of air or atmospheric oxygen, as in
the quick process of making vinegar; or——by submitting them, in
combination with ferments, to contact with a free supply of atmospheric
air, as in the old field process of making vinegar; or——by exposure to the
direct action of chemical or mechanical oxidizing agents, as condensed air
(platinum-black process), chromic and nitric acid, &c. In general, it is
alcohol more or less dilute, particularly as it exists in fermented
liquors, which is thus converted into acetic acid. In the second process
(destructive distillation), wood is the substance usually employed, and
heat is the agent which develops the acid.
The conversion of alcohol into acetic acid is not immediate and direct.
The atmospheric oxygen first oxidises two atoms of its hydrogen, aldehyd
and water being formed; and this aldehyd uniting with one atom of oxygen
produces one molecule of ACETIC ACID. The changes are represented in the
following equations:——
Alcohol. Oxygen. Aldehyd. Water.
=1.= C_{2}H_{6}O + O = C_{2}H_{4}O + H_{2}O
Aldehyd. Oxygen. Acetic Acid.
=2.= C_{2}H_{4}O + O = HC_{2}H_{3}O_{2}
After the first formation of aldehyd, the two processes, unless
artificially checked, go on simultaneously, as long as any undecomposed
alcohol is present.
The conversion of alcohol into acetic acid, although greatly accelerated
by the presence of nitrogenised organic matter (according to Mulder, of a
fungus——the _Mycoderma Vini_ or Vinegar Plant), is rather a case of
eremacausis (slow combustion) than of fermentation. Acetification effects
combination, as shown by the foregoing equations, whereas fermentation
resolves complex bodies into simpler ones, _e.g._ sugar into alcohol and
carbonic anhydride. Moreover, the presence of ferments is not essential to
the change, since pure alcohol becomes acetified when exposed to the
oxidising agents already named.
Another remarkable distinction between acetification and fermentation is,
that the former requires the continued presence of atmospheric oxygen;
whilst the vinous fermentation after being once established, proceeds
perfectly without it.
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