Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
The quantity of real acid it contained is then deduced by the following
calculation:——One equivalent of gaseous carbonic anhydride, or anhydrous
carbonic acid (= 44) bears the same proportion to one equivalent of the
acid in question, as the amount of the carbonic anhydride expelled does to
the amount of the acid sought. Thus, suppose a dilute sulphuric acid
expels 3 gr. of carbonic anhydride, the arrangement is——
44 : 49 :: 3 : 3·349
Consequently the sample operated on contained 3·5 (nearly) grains of true
sulphuric acid.
Instead of the above calculation, we may multiply the weights of the
respective acids required to expel 1 gr. of carbonic acid (as exhibited in
the following table) by the number of gr. of dry carbonic acid evolved
during the above operation. The product represents the per-centage
strength, when 100 gr. of the acid have been examined. When only 50, 25,
20, or 10 gr. have been tested, this product must, of course, be doubled,
quadrupled, &c., as the case may be.
TABLE II.
Multipliers.
Acetic acid (anhydrous) 1·159
” ” (hydrated or glacial) 1·364
Citric acid (crystallised) 1·523
Hydrochloric acid (dry or gaseous) ·829
” ” (sp. gr. 1·16) 2·478
Nitric acid (anhydrous) 1·227
” ” (sp. gr. 1·5) 1·523
” ” (sp. gr. 1·42) 2·045
Oxalic acid (crystallised) 1·432
Sulphuric acid (anhydrous) ·909
” ” (sp. gr. 1·8485) 1·114
Tartaric acid (anhydrous) 1·500
” ” (crystallised) 1·705
Even this easy calculation may be avoided, in technical analysis, by
simply taking for the assay such a weight of the respective acids as is
capable of disengaging exactly 10 gr. of dry carbonic acid from the
bicarbonate. In this case, the loss of weight in grains, from the
operation, multiplied by 10, at once indicates the exact per-centage
strength sought. The proper weight of any acid to be taken to give
per-centage results is found by simply dividing ten times the equiv. of
that acid by 44. For, taking sulphuric acid as an example,
as—— 44: 49 :: 10 : 11·1318
or 11·13 nearly.
On this principle are obtained the weights to be taken, as given in——
TABLE III.
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