Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume ICooley, Arnold James
Science
Cooley's Cyclopædia of Practical Receipts and Collateral Information in the Arts, Manufactures, Professions, and Trades..., Sixth Edition, Volume I
Cooley, Arnold James
Formulas, recipes, etc.; Industrial arts -- Dictionaries; Technology -- Dictionaries
Grains.
Acetic acid (anhydrous) 11·59
” ” (hydrated or glacial) 13·64
Citric acid (crystallised) 15·23
Hydrochloric acid (dry or gaseous) 8·29
” ” (sp. gr. 1·16) 24·78
Nitric acid (anhydrous) 12·27
” ” (sp. gr. 1·5) 15·23
” ” (sp. gr. 1·42) 20·45
Oxalic acid (crystallised) 14·32
Sulphuric acid (anhydrous) 9·09
” ” (sp. gr. 1·845) 11·14
Tartaric acid (anhydrous) 15·00
” ” (crystallised) 17·05
2. A convenient modification of the preceding method of acidimetry
consists in using the common apparatus figured in the margin and employing
fused chloride of calcium to dry the evolved carbonic acid gas, instead of
concentrated sulphuric acid. The mode of conducting the process and
obtaining the results is precisely the same as in that last explained, and
need not, therefore, be repeated. In this case, however, suction must be
applied to the small tube (_g_), instead of (_d_) in the accompanying
engraving.
_Obs._ These methods, though apparently complicated, are not difficult to
perform, when once well understood. The application of heat after the
completion of the operation is indispensable, as, if it were neglected,
from 0·3 to 0·4 of a gr. of carbonic acid would be retained in the liquid.
The bicarbonate of soda must be pure, and perfectly free from any neutral
carbonate or sesquicarbonate of soda. To ensure this, the bicarbonate of
commerce is reduced to a uniform powder, put into a glass jar, and covered
with its own weight of cold distilled or rain water, and allowed to stand
for twenty-four hours, with frequent stirring. It is then placed upon a
funnel, the tube of which is stopped with loose cotton, so as to allow the
lye to drain off. It is next washed several times with small quantities of
cold distilled or rain water, and after being dried by pressure between
some sheets of blotting-paper, without the aid of heat, is kept for use in
a well-closed glass bottle. Before use, it may be tested to ascertain its
purity. If pure, it neither reddens turmeric paper, nor gives a brick-red
precipitate with a solution of bichloride of mercury. Pure bicarbonate of
potassa may be used instead of bicarbonate of soda; but in either case it
is always proper to use an excess, so as to leave some undecomposed
carbonate after the operation has ended. The presence of a little sodium
chloride or sulphate in the bicarbonate will not interfere in the least,
but the absence of every trace of neutral carbonate is a _sine quâ non_.
[Illustration:
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account